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Chinese Journal of Organic Chemistry >

2021 , Vol. 41 >Issue 1: 276 - 283

DOI: https://doi.org/10.6023/cjoc202007046

Article

Borrowing Hydrogen Reductive Coupling of Nitroarenes with Benzyl Alcohols to Imines Catalyzed by Pd Nanoparticles on N Doped Carbon Materials

  • Jianing Che ,
  • Tao Song ,
  • Xianchi Gao ,
  • Yong Yang
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  • a College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong 266101
    b Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, Shandong 266101

Received date: 2020-07-19

  Revised date: 2020-08-17

  Online published: 2020-09-09

Supported by

the Key Technology R & D Program of Shandong Province(2019GGX102075)

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Abstract

Imines as a versatile organic synthetic intermediates have important applications in pharmaceuticals, dyes, and fine chemicals. In this work, heterogeneous Pd nanoparticles (Pd@N,O-carbon) on N doped carbon materials were developed using bamboo shoot as raw materials for highly efficient reductive coupling of nitroarenes with alcohols to selectively synthesize imines via the borrowing hydrogen strategy. The catalyst has obvious advantages in catalytic performance compared with other commercial catalysts or supports. Meanwhile, a broad set of complex imines were successfully synthesized in good yields with various functional groups tolerance for both nitroarenes and alcohols. This heterogeneous catalyst can also be recycled at several times without significant loss in activity and selectivity.

Key words： N doped carbon materials; Pd nanoparticles; nitroarenes; benzyl alcohols; borrowing hydrogen; imines

Cite this article

Jianing Che , Tao Song , Xianchi Gao , Yong Yang . Borrowing Hydrogen Reductive Coupling of Nitroarenes with Benzyl Alcohols to Imines Catalyzed by Pd Nanoparticles on N Doped Carbon Materials[J]. Chinese Journal of Organic Chemistry, 2021 , 41(1) : 276 -283 . DOI: 10.6023/cjoc202007046

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