Chinese Journal of Organic Chemistry >
Recent Advances in Cross-Dehydrogenative-Coupling Reactions Using Molecular Oxygen as the Sole Oxidant
Received date: 2020-07-02
Revised date: 2020-08-23
Online published: 2020-10-28
Supported by
the National Natural Science Foundation of China(21872028); the Foundation of Fujian Educational Committee(JZ160424); the Fujian Province University Fund for New Century Excellent Talents()
Cross-dehydrogenative-coupling (CDC) reactions have emerged as one of the most efficient and straightforward methods for the formation of C—C bonds or C-heteroatom bonds. However, most CDC reactions require hazardous and stoichiometric oxidants, such as PhI(OAc)2, benzoquinone, copper(II) salts, organic peroxide acid and silver(I) salts. A green and environmentary benign approach is using molecular oxygen (O2) as oxidant in the reactions, which usually form water as by-product. According to the classification of catalysts, the research progress of cross dehydrogenation coupling reaction with oxygen as the only oxidant is reviewed.
Key words： cross-dehydrogenative-coupling; molecular oxygen; oxidant
Weihui Zhuang , Xiaofeng Zhang , Qiufeng Huang . Recent Advances in Cross-Dehydrogenative-Coupling Reactions Using Molecular Oxygen as the Sole Oxidant[J]. Chinese Journal of Organic Chemistry, 2021 , 41(2) : 529 -542 . DOI: 10.6023/cjoc202007007
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