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Research Progress of Cellulose and Its Derivatives Supported Copper Catalyst Catalyzed Organic Reactions

  • Xin Chen ,
  • Chunxia Chen ,
  • Jinsong Peng
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  • a College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040
    b Material Science and Engineering College, Northeast Forestry University, Harbin 150040
* Corresponding authors. E-mail: ;

Received date: 2020-07-28

  Revised date: 2020-10-23

  Online published: 2020-11-19

Supported by

Natural Science Foundation of Heilongjiang Province(LC2018003); Fundamental Research Funds for the Central Universities(2572019CG06)

Abstract

Cellulose, the most abundant natural polymer in nature, is found in vascular plant, cotton, algae and bacteria, and it can be widely employed in organic synthesis and catalytic chemistry as a loading material for metal nanoparticles. In modern times, the field of transition metal catalysis has been developed rapidly, but it has the disadvantages of high cost, difficulty of separation and non-recyclable reuse, thus more and more researchers use cellulose and its derivatives to carry out heterogeneous catalysis. From an economic and efficient point of view, cheap cellulose and its derivatives-loaded copper particles can not only participate in various types of organic conversion efficiently, but also can be recycled and reused many times, thus solving many disadvantages of homogeneous catalysts and achieving green process. The organic reactions catalyzed by different types of cellulose-supported copper catalysts are reviewed, including the construction of C—X bond, cycloaddition, oxidation, reduction, photocatalytic degradation and electrocatalysis. It will promote the application of cellulose and its derivatives-sup- ported catalysts in the future.

Cite this article

Xin Chen , Chunxia Chen , Jinsong Peng . Research Progress of Cellulose and Its Derivatives Supported Copper Catalyst Catalyzed Organic Reactions[J]. Chinese Journal of Organic Chemistry, 2021 , 41(4) : 1319 -1336 . DOI: 10.6023/cjoc202007063

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