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Chinese Journal of Organic Chemistry >

2021 , Vol. 41 >Issue 4: 1337 - 1358

DOI: https://doi.org/10.6023/cjoc202009031

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Advances in Deallylation

  • Yu Wang ,
  • Jingyang Wang ,
  • Xiaoyu Wu ,
  • Guangni Ding ,
  • Zhaoguo Zhang ,
  • Xiaomin Xie
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  • a School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240
    b School of Materials Science and Engineering, Nanchang University, Nanchang 330031
* Corresponding authors. E-mail: ;
E-mail:

Received date: 2020-09-13

  Revised date: 2020-10-28

  Online published: 2020-11-19

Supported by

National Natural Science Foundation of China(21672143); Interdisciplinary Program of Shanghai Jiao Tong University(YG2017MS26)

Fold

Abstract

Allyl groups, as a kind of universal protective groups in organic synthesis, are easily introduced, and stable under acidic, basic and reductive conditions. Moreover, the deallylation may occur efficiently and selectively under mild conditions. Therefore, functional group protection with allyl moiety plays a significant role in organic synthesis, especially in the synthesis of natural products and pharmaceutical industry. In recent decades, various methods of deallylation have been developed. Herein, the comprehensive development on the deallylation reaction with base and reductant, oxidation and free radical, Lewis-acid, iodine, transition metals, and electrochemical methods is reviewed.

Key words： deallylation; base-catalyzed deallylation; transition metal catalyzed deallylation; oxidative deallylation; free radical deallylation; Lewis-acid catalyzed deallylation; electrochemical deallylation

Cite this article

Yu Wang , Jingyang Wang , Xiaoyu Wu , Guangni Ding , Zhaoguo Zhang , Xiaomin Xie . Advances in Deallylation[J]. Chinese Journal of Organic Chemistry, 2021 , 41(4) : 1337 -1358 . DOI: 10.6023/cjoc202009031

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