Chinese Journal of Organic Chemistry >
High Efficient Synthesis of Monofluoromethyldisulfides
Received date: 2020-09-01
Revised date: 2020-11-02
Online published: 2020-12-01
Supported by
Natural Science Foundation of Shanghai(20ZR1471600); Science and Technology Commission of Shanghai Municipality(19DZ2271100); Open Research Fund Program of CAS Key Laboratory Of Energy Regulation Materials(ORFP2020-06)
The monofluoromethylthiolation reaction of thiophenols/mercaptans was developed at room temperature using PhSO2SCH2F as monofluoromethylthiolation reagent, and a series of monofluoromethyl disulfides were synthesized in good yields. This method features short reaction time, mild conditions, simple operation and no additives. It provides a simple and convenient way for the efficient preparation of monofluoromethyl disulfides.
Key words: monofluoromethylthio; disulfide; PhSO2SCH2F; thiophenol
Xiaoguang Hu , Renyi Pang , Tianjiao Zheng , Ruichao Yao , Wenbo Chen . High Efficient Synthesis of Monofluoromethyldisulfides[J]. Chinese Journal of Organic Chemistry, 2021 , 41(3) : 1117 -1123 . DOI: 10.6023/cjoc202009001
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