Chinese Journal of Organic Chemistry >
Alternative Approach for the Synthesis of Nitroaromatic Olefins via Dehydrogenative Nitration of Easily Available Arylethanes
Received date: 2020-08-24
Revised date: 2020-11-27
Online published: 2021-02-07
Supported by
the National Natural Science Foundation of China(21702191)
Nitroolefin is a common and versatile reagent, synthesis of which from aldehydes/ketones, α, β-unsaturated carboxylic acids or olefins is generally limited by the high cost of raw materials in industrial processes in the future. Herein, an alternative and economical protocol for the synthesis of nitroaromatic olefins directly from easily available arylethanes with barium nitrate using Cu/Ag as cocatalyst and ammonium persulfate as the terminal oxidant is reported. Additionally, 1,1-diphenylethanes, phenylethanes, 4-ethyl-1,1'-biphenyl and ethylnaphthalenes were suitable substrates for the current dehydrogenative nitration, and provided E-nitroaromatic olefins in moderate to good yields.
Bing Mu , Junliang Wu , Guang'an Zhang . Alternative Approach for the Synthesis of Nitroaromatic Olefins via Dehydrogenative Nitration of Easily Available Arylethanes[J]. Chinese Journal of Organic Chemistry, 2021 , 41(1) : 250 -257 . DOI: 10.6023/cjoc202008041
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