Chinese Journal of Organic Chemistry >
Recent Development of Samarium Diiodide and Other Samarium Reagents in Organic Transformation
Received date: 2020-11-25
Revised date: 2021-01-28
Online published: 2021-02-26
Supported by
Shandong Provincial Key Research and Development Program(2019GGXI02036)
Since the samarium diiodide was discovered, it has been occupying a key field in organic synthesis due to the excellent ability of both single electron transfer and reduction. Other samarium reagents have also been wildly developed in recent years, such as Sm, allylSmBr, SmI3and so on. In this review, the reactions mediated by samarium reagents especially SmI2 in latest five years are summarized. It mainly includes three parts: studies on the SmI2 promoted coupling reactions, studies on the coupling reactions promoted by other samarium reagents (Sm, allylSmBr, SmI3, Sm(OTf)3 etc.), and studies on the samarium reagents promoted organic reduction reactions.
Chen Liu , Yan Qi , Yongjun Liu . Recent Development of Samarium Diiodide and Other Samarium Reagents in Organic Transformation[J]. Chinese Journal of Organic Chemistry, 2021 , 41(6) : 2202 -2216 . DOI: 10.6023/cjoc202011034
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