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Chinese Journal of Organic Chemistry >

2021 , Vol. 41 >Issue 6: 2302 - 2309

DOI: https://doi.org/10.6023/cjoc202102002

ARTICLES

Copper-Catalyzed Vicinal C(sp2)—H Selenylation of Benzoic Acid Derivatives Using Air as Oxidant

  • Mingyang Sun ,
  • Kun Xu ,
  • Bingbing Guo ,
  • Chengchu Zeng
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  • Faculty of Enviroment and Life Science, Beijing University of Technology, Beijing 100124
*Corresponding author.E-mail:

Received date: 2021-02-01

  Revised date: 2021-02-28

  Online published: 2021-03-12

Supported by

National Natural Science Foundation of China(21871019)

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Abstract

An efficient copper-catalyzed vicinal C(sp2)―H selenylation of benzoic acid dervatives is reported using diselenyl ether as selenyl resource, 8-aminoquinoline as the directing group. The protocol need only air as the terminal oxidant, avoiding the utilization of other external chemical oxidants, featuring good substrates generality and compatiblity of functional groups.

Key words： copper-catalyzed; C—H activation; selenylation reaction; diselenyl ether; 8-aminoquinoline

Cite this article

Mingyang Sun , Kun Xu , Bingbing Guo , Chengchu Zeng . Copper-Catalyzed Vicinal C(sp2)—H Selenylation of Benzoic Acid Derivatives Using Air as Oxidant[J]. Chinese Journal of Organic Chemistry, 2021 , 41(6) : 2302 -2309 . DOI: 10.6023/cjoc202102002

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