Chinese Journal of Organic Chemistry >
Recent Progress in Iridium-Catalyzed Remote Regioselective C—H Borylation of (Hetero)Arenes
Received date: 2021-03-10
Revised date: 2021-03-17
Online published: 2021-03-25
Supported by
National Natural Science Foundation of China(91956116)
(Hetero)Aryl boronic acids and their derivatives have been widely used in synthetic chemistry, material sciences, and drug discovery. Accordingly, the development of novel synthetic methods towards these structures has received a great deal of attention. In particular, Ir-catalyzed C—H borylation represents one of the most efficient methods. Due to the restriction of the reaction mechanism, regioselective controllable C—H borylation of Ir catalysis is a formidable challenge, and it is also an important development direction in this area. In this review, the recent progress in Ir-catalyzed remote selective C—H borylation of arenes is systematically discussed.
Key words： C—H activation; (hetero)aryl boronates; synthetic methods; borylation
Xiaoliang Zou , Senmiao Xu . Recent Progress in Iridium-Catalyzed Remote Regioselective C—H Borylation of (Hetero)Arenes[J]. Chinese Journal of Organic Chemistry, 2021 , 41(7) : 2610 -2620 . DOI: 10.6023/cjoc202103020
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