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Chinese Journal of Organic Chemistry >

2021 , Vol. 41 >Issue 8: 3279 - 3284

DOI: https://doi.org/10.6023/cjoc202103018

NOTES

Alkoxylation of para-Quinone Methides via Bismuth Complex Catalyzed 1,6-Addition Reactions of Alcohols

  • Hanlin Li ,
  • Donglan Liu ,
  • Liang Chen ,
  • Haiyan Xu ,
  • Hongfei Lu
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  • School of Environmental and Chemical Engineering, Jiangsu University of Science and Techonology, Zhenjiang 212100
*Corresponding authors. E-mail: ;
E-mail:

Received date: 2021-03-08

  Revised date: 2021-04-25

  Online published: 2021-06-02

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Abstract

An effective 1,6-addition route for para-quinone methides (p-QMs) to synthesize bismuth-catalyzed substituted diarylmethanes was developed. The key feature of this transformation in our methodology is that the metallic bismuth complexes are inexpensive, untapped, overlooked, and reusable, making the reaction more sustainable. Moreover, this protocol provides facile access to a class of deviratives of diaryl and triarylmenthanes with good to excellent yields and good tolerance of the functional groups. A feasible and appealing solution is delivered by convenient work-up and mild reaction conditions.

Key words： p-QMs; bismuth-catalysis; 1,6-addition

Cite this article

Hanlin Li , Donglan Liu , Liang Chen , Haiyan Xu , Hongfei Lu . Alkoxylation of para-Quinone Methides via Bismuth Complex Catalyzed 1,6-Addition Reactions of Alcohols[J]. Chinese Journal of Organic Chemistry, 2021 , 41(8) : 3279 -3284 . DOI: 10.6023/cjoc202103018

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