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Chinese Journal of Organic Chemistry >

2021 , Vol. 41 >Issue 9: 3710 - 3716

DOI: https://doi.org/10.6023/cjoc202104033

NOTES

A Catalyst-Free One-Pot Protocol for the Construction of Substituted Sulfonyl Pyrazoles

  • Haojie Ma ,
  • Xiaoqiang Zhou ,
  • Bo Han ,
  • Ran Li ,
  • Xueyan Hou ,
  • Xingyue Ji ,
  • Yuqi Zhang ,
  • Guosheng Huang ,
  • Jijiang Wang
Expand
  • a Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000
    b State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000
    c College of Chemistry and Material, Weinan Normal University, Weinan, Shaanxi 714099
* Corresponding authors. E-mail: ;
*

Received date: 2021-04-16

  Revised date: 2021-04-27

  Online published: 2021-06-22

Supported by

National Natural Science Foundation of China(21663032); National Natural Science Foundation of China(31701679); National Natural Science Foundation of China(22061041); PhD Research Startup Foundation of Yan'an University(YDBK2019-30); PhD Research Startup Foundation of Yan'an University(YDBK2015-11); Municipal Special Fund of Yan'an for High-Level Talents(2019-29); Yan'an University Training Program of Innovation and Entrepreneurship for Undergraduates(D2019016); Natural Science Basic Research Program of Shaanxi Province(2019JQ-902); Scientific Research Program Funded by Shaanxi Provincial Education Department(19JK0287)

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Abstract

A novel and efficient protocol for the construction of substituted pyrazoles from benzenesulfonohydrazides and pentane-2,4-diones under catalyst-free conditions was developed. This protocol features excellent tolerance to a variety of functional groups, step economy, simple operation with inexpensive reagents, mild reaction conditions, and can be scaled-up.

Key words： catalyst-free; sulfonyl pyrazole; pentane-2,4-dione; benzenesulfonohydrazide

Cite this article

Haojie Ma , Xiaoqiang Zhou , Bo Han , Ran Li , Xueyan Hou , Xingyue Ji , Yuqi Zhang , Guosheng Huang , Jijiang Wang . A Catalyst-Free One-Pot Protocol for the Construction of Substituted Sulfonyl Pyrazoles[J]. Chinese Journal of Organic Chemistry, 2021 , 41(9) : 3710 -3716 . DOI: 10.6023/cjoc202104033

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