Chinese Journal of Organic Chemistry >
Tetraphenylethylene-Based Tetradentate Azolium Salts: Synthesis and Selective Recognition for Ions
Received date: 2021-03-05
Revised date: 2021-03-24
Online published: 2021-07-06
Supported by
Tianjin Natural Science Foundation(18JCZDJC99600); National Natural Science Foundation of China(21572159); Program for Innovative Research Team in University of Tianjin(TD13-5074)
Two new tetraphenylethylene-based tetradentate azolium salts, 1,1,2,2-tetrakis{[2'-(N-methyl-imidazolium-1-yl)ethoxyl]phenyl}ethylene hexafluorophosphate (1) and 1,1,2,2-tetrakis{[2'-(N-picolyl-benzimidazolium-1-yl)ethoxyl]phenyl}ethylene hexafluorophosphate (2), were synthesized and characterized. Recognitions of 1 for anions and 2 for cations were studied through fluorescence spectra, UV/vis spectra, HRMS, 1H NMR and infrared spectroscopies. The results revealed that 1 was able to differentiate $H_{2}PO_{4}^-$ from other anions, and 2 was able to differentiate Ag+ from other cations via fluorescence method.
Key words： tetraphenylethylene; azolium salts; fluorescence; recognition; ions
Xinying Li , Zhixiang Zhao , Linhai Hu , Dengche Wei , Qingxiang Liu . Tetraphenylethylene-Based Tetradentate Azolium Salts: Synthesis and Selective Recognition for Ions[J]. Chinese Journal of Organic Chemistry, 2021 , 41(9) : 3608 -3616 . DOI: 10.6023/cjoc202103011
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