Chinese Journal of Organic Chemistry >
Recent Advances in Synergistic Catalysis by Merging N-Heterocyclic Carbenes and Transition Metals
Received date: 2021-06-01
Revised date: 2021-07-02
Online published: 2021-08-19
Supported by
National Natural Science Foundation of China(21572270); National Natural Science Foundation of China(21702232); “Double First-Class” University Project(CPU2018GY02); “Double First-Class” University Project(CPU2018GY35); Fundamental Research Funds for the Central Universities(2632021ZD19)
Unique reaction modes, diverse reaction sites, and structural diversity of both substrates and products have made N-heterocyclic carbene catalysis be of great of importance in the field of organic catalysis. However, there have been a lot of barriers and challenges in terms of the reactivity of substrates and the selectivity of reactions for traditional and single catalytic systems with the deep development of organic synthesis. Recently, synergistic catalysis makes it possible for previously inaccessible transformations and can adjust the reactivity and selectivity more accurately by merging two single catalytic systems, thus has emerged as a powerful catalytic strategy in organic synthesis. In this review, the latest research progress in the field of synergistic catalysis of N-heterocyclic carbenes and transition metals in the last decade is mainly reviewed.
Jianming Zhang , Jian Gao , Jie Feng , Tao Lu , Ding Du . Recent Advances in Synergistic Catalysis by Merging N-Heterocyclic Carbenes and Transition Metals[J]. Chinese Journal of Organic Chemistry, 2021 , 41(10) : 3792 -3807 . DOI: 10.6023/cjoc202106002
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