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Chinese Journal of Organic Chemistry >

2021 , Vol. 41 >Issue 11: 4338 - 4346

DOI: https://doi.org/10.6023/cjoc202106048

ARTICLES

tBuOK-Promoted Reaction of Selenocyanates and Hydrazones for the Synthesis of Selenoacetals

  • Hao Ye ,
  • Tingting Ren ,
  • Xinxing Wu
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  • a College of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019
    b Jiangsu Huachuang Testing Technical Service Co., Ltd., Nantong, Jiangsu 226019
* Corresponding author. E-mail:

Received date: 2021-06-25

  Revised date: 2021-07-28

  Online published: 2021-08-25

Supported by

Program of High-level Talents of Nantong University(03083031)

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Abstract

A series of selenoacetals were synthesized from selenocyanates and hydrazones under base condition. (Hetero)aryl selenocyanate and (hetero)aryl, alkyl hydrazones can undergo the process successfully, and shows broad substrate scope and excellent functional group tolerance. This protocol is suitable for gram-scale preparation, providing an efficient and practical synthetic strategy toward selenoacetals.

Key words： selenocyanate; hydrazone; selenoacetal; rearrangement

Cite this article

Hao Ye , Tingting Ren , Xinxing Wu . tBuOK-Promoted Reaction of Selenocyanates and Hydrazones for the Synthesis of Selenoacetals[J]. Chinese Journal of Organic Chemistry, 2021 , 41(11) : 4338 -4346 . DOI: 10.6023/cjoc202106048

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