Chinese Journal of Organic Chemistry >
Application of α-Keto Acids in Metal-Free Photocatalysis
Received date: 2021-09-04
Revised date: 2021-10-13
Online published: 2021-10-21
Supported by
National Natural Science Foundation of China(21971224); National Natural Science Foundation of China(22171249); Innovation and Entrepreneurship Training Program(S202110459196); Innovation and Entrepreneurship Training Program(2021cxcy197); Top Undergraduates Program of Zhengzhou University
As a carboxylic acid, α-keto acid can be used as an acylating reagent by decarboxylation in organic synthesis. However, traditional methods often need transition metal catalysts or high temperatures, which limits the application of α-keto acid to a certain extent. In recent years, organic transformations induced by visible light have attracted extensive attention due to its mild conditions and simple operations. Herein, the recent advances of metal-free photocatalytic application of α-keto acids are summarized, which mainly include acylation reactions and cyclization reactions.
Key words： α-keto acid; visible light; metal-free catalysis; acylation
Kunchen Xie , Mingxuan Jiang , Xiaolan Chen , Qiyan Lü , Bing Yu . Application of α-Keto Acids in Metal-Free Photocatalysis[J]. Chinese Journal of Organic Chemistry, 2021 , 41(12) : 4575 -4587 . DOI: 10.6023/cjoc202109008
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