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Chinese Journal of Organic Chemistry >

2021 , Vol. 41 >Issue 12: 4766 - 4772

DOI: https://doi.org/10.6023/cjoc202109044

ARTICLES

Electrochemical Selenylation of N-Unprotected Anilines for Consturcing 4-(Organylselanyl)anilines

  • Wenyi Li ,
  • Yinheng Tang ,
  • Wentao Ouyang ,
  • Yuhan Lu ,
  • Jinyang Chen ,
  • Weimin He
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  • a College of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421000
    b School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan 421001
* Corresponding authors. E-mail: ;

Received date: 2021-09-28

  Revised date: 2021-10-30

  Online published: 2021-11-03

Supported by

National Natural Science Foundation of China(21902014); National Natural Science Foundation of China(22002037); Scientific Research Hunan Provincial Education Department(19A068)

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Abstract

A transition-metal-free and chemical oxidant-free method was developed for the uniform synthesis of 4-arylselanylanilines and 4-alkylselanylanilines through electrolytic selenylation of N-unprotected anilines with diorganyl diselenides under mild conditions in an undivided cell. The present approach had good functional group compatibility, which made it to be a green and practical method to synthesize 4-(organylselanyl)anilines.

Key words： N-unprotected anilines; diorganyl diselenides; electrochemical synthesis; mild conditions; green chemistry

Cite this article

Wenyi Li , Yinheng Tang , Wentao Ouyang , Yuhan Lu , Jinyang Chen , Weimin He . Electrochemical Selenylation of N-Unprotected Anilines for Consturcing 4-(Organylselanyl)anilines[J]. Chinese Journal of Organic Chemistry, 2021 , 41(12) : 4766 -4772 . DOI: 10.6023/cjoc202109044

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