Chinese Journal of Organic Chemistry >
Visible Light-Mediated Metal-Free Decarboxylative Deuteration of Carboxylic Acid
Received date: 2021-11-06
Revised date: 2021-12-11
Online published: 2021-12-15
Supported by
National Natural Science Foundation of China(21502046)
A metal-free visible light-induced decarboxylation of phenylacetic acid derivatives has been successfully developed. Without the additives, direct decarboxylative monodeuteration of acids was successfully achieved using cheap deuterium sources. Besides, in presence of air, similar catalytic systems provided ketone products.
Key words： photochemistry; metal-free; decarboxylation; deuteration
Yuhang He , Hui Yang , Dongxu Gao , Jiahui Ma , Yamin Shao , Guanghui An , Guangming Li . Visible Light-Mediated Metal-Free Decarboxylative Deuteration of Carboxylic Acid[J]. Chinese Journal of Organic Chemistry, 2021 , 41(12) : 4725 -4731 . DOI: 10.6023/cjoc202111014
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