Chinese Journal of Organic Chemistry >
Design and Synthesis of a Zn2+ Fluorescent Probe Based on Aggregation Induced Luminescence Properties
Received date: 2022-07-03
Revised date: 2022-08-01
Online published: 2022-09-02
Supported by
Shaanxi Provincial Technology Innovation Guidance Special Fund(2022QFY09-09); Shaanxi Province Key Research Program(2020GY-246); Natural Science Foundation of Shaanxi Province(S2018-JC-QN-0631); Special Scientific Research Project of Shaanxi Provincial Department of Education(17JK0017); Special Scientific Research Project of Shaanxi Provincial Department of Education(20JK0473); Key Laboratory of Se-Enriched Products Development and Quality Control, Ministry of Agriculture(Se-2020C04); National Undergraduate Training Program for Innovation and Entrepreneurship(S202111397012); Shaanxi Provincial Innovation Experiment Program for University Students(S202111397039)
In this paper, a novel aggregation-induced emission (AIE) effect Zn2+ fluorescent probe L was constructed with aggregation-induced emission (AIE), tetraphenylethylene as the fluorescent group and 5-tert-butyl-2-hydroxybenzene as the recognition group. The structure of probe L was characterized by NMR and ESI-MS, and its fluorescence properties was studied by UV-vis and fluorescence spectroscopy. In ethanol/phosphate (PBS) (V∶V=7∶3, pH=7.4) solution, the probe L exhibited fluorescence-enhanced high selectivity and sensitivity detection of Zn2+, the detection limit was 34.1 nmol•L–1. In the range of 0~3.0×10–5 mol•L–1, the probe showed a good linear relationship to Zn2+. The obvious color change can be observed with the naked eye under UV light and natural light, which can realize the visual detection of Zn2+. The response mechanism of the probe to Zn2+ was studied by Job’s plot, ESI-MS and density functional theory (DFT) theoretical calculation. The novel probe reported in this paper can serve as a convenient tool for the analytical determination of Zn2+.
Jidong Zhang , Wanlin Yan , Wenqiang Hu , Dian Guo , Dalong Zhang , Xiaoxin Quan , Xianpan Bu , Siyu Chen . Design and Synthesis of a Zn2+ Fluorescent Probe Based on Aggregation Induced Luminescence Properties[J]. Chinese Journal of Organic Chemistry, 2023 , 43(1) : 326 -331 . DOI: 10.6023/cjoc202207004
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