Chinese Journal of Organic Chemistry >
N-Heterocyclic Carbene-Pyridine Manganese Complex/ Tetrabutylammonium Iodide Catalyzed Synthesis of Cyclic Carbonate from CO2 and Epoxide
Received date: 2022-09-08
Revised date: 2022-09-29
Online published: 2022-11-08
Supported by
Bingtuan Young and Middle-Aged Innovative Leading Scientists Program(2020CB027); Shihezi Young and Middle- Aged Innovative Leading Scientists Program(2019RC01)
The bidentate N-heterocyclic carbene (NHC)-pyridine nitrogen manganese complex catalyzed coupling reaction of epoxides with CO2 was developed. The binary system resulting from the manganese complex Mn-2 in combination with tetrabutylammonium iodide (TBAI) exhibits the high activity for the synthesis of cyclic carbonate from epoxides and CO2. The binary catalytic system is suitable for a broad range of substrates scope, such as terminal epoxides and sterically hindered internal epoxides. A possible catalytic pathway was elaborated by UV-vis, FT-IR and HRMS method.
Guijie Liu , Zhengqiang Fu , Fei Chen , Caixia Xu , Min Li , Ning Liu . N-Heterocyclic Carbene-Pyridine Manganese Complex/ Tetrabutylammonium Iodide Catalyzed Synthesis of Cyclic Carbonate from CO2 and Epoxide[J]. Chinese Journal of Organic Chemistry, 2023 , 43(2) : 629 -635 . DOI: 10.6023/cjoc202206047
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