Chinese Journal of Organic Chemistry >
Recent Advances in Transition Metal-Catalyzed B—H Bond Activation for Synthesis of o-Carborane Derivatives with B—Heteroatom Bond
Received date: 2022-11-30
Revised date: 2022-12-23
Online published: 2023-01-05
Supported by
National Natural Science Foundation of China(92056106); Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Chinese Academy of Sciences
Carboranes are a class of carbon-boron molecular clusters with exceptional thermal and chemical stabilities. They are finding a variety of applications in medicine, materials, and coordination/organometallic chemistry as functional building blocks. Recently, transition metal catalyzed regioselective o-carborane B—H activation has been rapidly developed, offering a series of novel methodologies for selective cage boron functionalization. The current state of functionalization of o-carboranes to form B—B, B—N, B—O, B—S, and B—halogen bonds using transition metal-catalyzed B—H activation strategy is summarized. Some reaction mechanisms are highlighted, and the future challenges and focus of the carborane B—heteroatom bond construction are discussed.
Key words： carborane; B—H activation; transition metal catalysis; B—heteroatom bond
Hairui Jia , Zaozao Qiu . Recent Advances in Transition Metal-Catalyzed B—H Bond Activation for Synthesis of o-Carborane Derivatives with B—Heteroatom Bond[J]. Chinese Journal of Organic Chemistry, 2023 , 43(3) : 1045 -1068 . DOI: 10.6023/cjoc202211040
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