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Chinese Journal of Organic Chemistry >

2023 , Vol. 43 >Issue 3: 914 - 923

DOI: https://doi.org/10.6023/cjoc202211041

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Recent Progress in Transition Metal Catalyzed C(sp3)—H Nitrene Insertion Reactions Assisted by Directing Groups

  • Xing Yang ,
  • Xu Liu ,
  • Lijia Wang
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  • a Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062
    b Shanghai Frontiers Science Center of Molecule Intelligent Syntheses, Shanghai 200062
* Corresponding author. E-mail:

Received date: 2022-11-30

  Revised date: 2023-02-01

  Online published: 2023-02-15

Supported by

National Natural Science Foundation of China(91956103)

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Abstract

The transition metal catalyzed activation of C(sp3)—H bonds to form carbon-nitrogen bonds has been a challenging and hot research area. The transition metal-catalyzed C(sp3)—H amination strategy provides a more direct and efficient way to form C—N bonds. With the vigorous development in the field of C—H bond activation, a variety of directing groups and transition metal catalyst systems have been developed, which provide effective tools for C(sp3)—H amination through the inner sphere mechanism. In recent years, important progress has been made in directing group-assisted C(sp3)—H bond amination reactions, and many catalyst systems based on different transition metals with cheap and efficient amination reagents have been developed. The research progress of transition metal-catalyzed C(sp3)—H nitrene insertion reaction assisted by directing groups in the past decade is reviewed.

Key words： directing group; nitrene insertion; transition metal; C(sp3)—H; C—N bond formation

Cite this article

Xing Yang , Xu Liu , Lijia Wang . Recent Progress in Transition Metal Catalyzed C(sp3)—H Nitrene Insertion Reactions Assisted by Directing Groups[J]. Chinese Journal of Organic Chemistry, 2023 , 43(3) : 914 -923 . DOI: 10.6023/cjoc202211041

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