Chinese Journal of Organic Chemistry >
Research Progress of Lewis Acid and Base Pairs Applied in Materials Chemistry
Received date: 2023-01-09
Revised date: 2023-02-07
Online published: 2023-02-15
Supported by
National Key R&D Program of China(2021YFA1501700); National Natural Science Foundation of China(51973232); National Natural Science Foundation of China(21821002); National Natural Science Foundation of China(52203020); National Natural Science Foundation of China(22201292)
Lewis Pairs (LPs) have made a rapid development in the fields of small molecule activation (such as CO2, H2, CO, SO2, N2O) and asymmetric catalysis, mainly thanks to the diversity of Lewis Pairs (LPs) synthesis and the convenient tunability of steric hindrance and electronic effects. The synthesis of novel functional polymer materials has always been a research hotspot in material chemistry. The introduction of Lewis acids (LAs) and Lewis bases (LBs) into the polymer skeleton can endow materials with unique properties and greatly enrich the types of functional polymer materials. Herein, this review summarizes the recent advance and synthesis of macro-LAs and macro-LBs, but also illustrates the diversity and versatility of LPs and Lewis pair polymerizations (LPPs) in the application of material chemistry. This review highlights the construction of supramolecular polymer networks, CO2 capture and release, and the synthesis of novel topological polymers. In addition, the challenges and the future development trend in this field are also proposed.
Lijuan Xiao , Yanping Zhang , Miao Hong . Research Progress of Lewis Acid and Base Pairs Applied in Materials Chemistry[J]. Chinese Journal of Organic Chemistry, 2023 , 43(3) : 949 -960 . DOI: 10.6023/cjoc202301009
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