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Chinese Journal of Organic Chemistry >

2023 , Vol. 43 >Issue 3: 1091 - 1101

DOI: https://doi.org/10.6023/cjoc202211028

ARTICLES

Copper-Catalyzed Allylic C(sp3)—H Sulfonylation of Cyclic Olefins

  • Chunyang Liu ,
  • Yan Li ,
  • Qian Zhang
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  • a Department of Chemistry, Northeast Normal University, Changchun 130024
    b State key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
* Corresponding authors. E-mail: ;

Received date: 2022-11-24

  Revised date: 2023-02-16

  Online published: 2023-03-01

Supported by

National Natural Science Foundation of China(22193012); National Natural Science Foundation of China(21831002); Fundamental Research Funds for the Central Universities(2412022ZD049)

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Abstract

A highly efficient copper-catalyzed direct sulfonylation of allylic C(sp3)—H bond was developed using simple cyclic olefins and sodium sulfite as starting materials. A series of allylic sulfone derivatives were synthesized in moderate to good yields under mild conditions. The mechanism study shows that the reaction might involve radical intermediates.

Key words： copper-catalyzed; radicals; allylic C(sp3)—H; sulfonation reaction; allylic sulfone

Cite this article

Chunyang Liu , Yan Li , Qian Zhang . Copper-Catalyzed Allylic C(sp3)—H Sulfonylation of Cyclic Olefins[J]. Chinese Journal of Organic Chemistry, 2023 , 43(3) : 1091 -1101 . DOI: 10.6023/cjoc202211028

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