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Chinese Journal of Organic Chemistry >

2023 , Vol. 43 >Issue 5: 1815 - 1823

DOI: https://doi.org/10.6023/cjoc202211033

ARTICLES

Electrochemical Synthesis of Masked Organoboronic Acids RB(dan) at Room Temperature

  • Junying Zhang ,
  • Xiaojing Zhao ,
  • Ganpeng Li ,
  • Yonghui He
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  • Key Laboratory of Chemistry in Ethnic Medicinal Resources, State Ethnic Affairs Commission & Ministry of Education, Key Laboratory of Natural Products Synthetic Biology of Ethnic Medicinal Endophytes, State Ethnic Affairs Commission, School of Ethnic Medicine, Yunnan Minzu University, Kunming, 650500
* Corresponding authors. E-mail: ;

Received date: 2022-11-27

  Revised date: 2023-02-19

  Online published: 2023-03-17

Supported by

National Natural Science Foundation of China(21662045); National Natural Science Foundation of China(11547233); Applied Basic Research Project of Yunnan Province(202101AT070079)

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Abstract

An electrochemical room-temperature synthesis of masked organoboronic acids RB(dan) (R=alkyl or aryl) has been developed. At room temperature, 1,8-diaminonaphthalene and boronic acids can smoothly participate in this reaction to provide a wide variety of RB(dan) (R=alkyl or aryl) in an undivided cell. The transformation has broad substrate scope and avoids using high-temperature or transition-metal catalysts, making it more sustainable and renewable.

Key words： electrochemical synthesis; boronic acids; masked group; room temperature

Cite this article

Junying Zhang , Xiaojing Zhao , Ganpeng Li , Yonghui He . Electrochemical Synthesis of Masked Organoboronic Acids RB(dan) at Room Temperature[J]. Chinese Journal of Organic Chemistry, 2023 , 43(5) : 1815 -1823 . DOI: 10.6023/cjoc202211033

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