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Chinese Journal of Organic Chemistry >

2023 , Vol. 43 >Issue 8: 2837 - 2847

DOI: https://doi.org/10.6023/cjoc202210028

A Metal-Free Photocatalytic Hydrosilylation of Alkenes Using Bromide Salt as a Hydrogen Atom Transfer Reagent

  • Yu Zhao ,
  • Kai Zhang ,
  • Yubin Bai ,
  • Yantu Zhang ,
  • Shihui Shi
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  • a College of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000
    b School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou, Jiangsu 221116
†These authors contributed equally to this work
*E-mail: ;

Received date: 2022-10-24

  Revised date: 2023-03-01

  Online published: 2023-04-23

Supported by

The National Natural Science Foundation of China(22161047); The National Natural Science Foundation of China(22101102); The Natural Science Basic Research Program of Shaanxi Province(2021JQ-609); The Science and Technology Department of Shaanxi Province(2019JM-516); The PhD Research Startup Foundation of Yan'an University(YDBK2018-30)

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Abstract

A metal-free photocatalytic hydrosilylation of alkenes through the selective activation of Si—H bond has been developed utilizing the readily available and cheaper bromide salt as the catalytic hydrogen atom transfer (HAT) reagent. This protocol features excellent functional group tolerance and broad substrate scope, affording the organosilicon compounds in moderate to excellent yields under a mild and redox-neutral process. This strategy was successfully applied for the introduction of the silyl group into bio-relevant active molecules.

Key words： photocatalysis; hydrogen atom transfer catalysis; silyl radical; organosilicon compound

Cite this article

Yu Zhao , Kai Zhang , Yubin Bai , Yantu Zhang , Shihui Shi . A Metal-Free Photocatalytic Hydrosilylation of Alkenes Using Bromide Salt as a Hydrogen Atom Transfer Reagent[J]. Chinese Journal of Organic Chemistry, 2023 , 43(8) : 2837 -2847 . DOI: 10.6023/cjoc202210028

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