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Chinese Journal of Organic Chemistry >

2023 , Vol. 43 >Issue 5: 1691 - 1705

DOI: https://doi.org/10.6023/cjoc202302022

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Recent Progress in meta-/para-Selective Aromatic C—H Borylation

  • Wang Jiang ,
  • Zhuangzhi Shi
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  • a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093
    b College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225000
* Corresponding author. E-mail:

Received date: 2023-02-22

  Revised date: 2023-04-25

  Online published: 2023-05-06

Supported by

National Natural Science Foundation of China(22025104); National Natural Science Foundation of China(22171134); National Natural Science Foundation of China(21972064); National Natural Science Foundation of China(21901111)

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Abstract

Organoboron compounds are important building blocks to create molecular diversity. Strategies that can transform the readily available hydrocarbons into these compounds by C—H borylation are highly attractive. In this context, significant progress has been made towards iridium-catalyzed C—H borylation. Because substituted arenes typically contain ortho-, meta- and para-C—H bonds, regiocontrol has been a long-standing challenge within this type of chemistry. During the past decade, significant progress has been made in the ortho-selective C—H borylation, while the meta-/para-selectivity is still challenging. This review aims to provide a comprehensive overview of this topic on meta-/para-selective aromatic C—H borylation by iridium catalysis. This topic is categorized into directed and non-directed C—H borylation.

Key words： meta selectivity; para selectivity; iridium catalysis; C—H borylation; directing groups

Cite this article

Wang Jiang , Zhuangzhi Shi . Recent Progress in meta-/para-Selective Aromatic C—H Borylation[J]. Chinese Journal of Organic Chemistry, 2023 , 43(5) : 1691 -1705 . DOI: 10.6023/cjoc202302022

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