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Chinese Journal of Organic Chemistry >

2023 , Vol. 43 >Issue 5: 1761 - 1771

DOI: https://doi.org/10.6023/cjoc202302027

ARTICLES

Cobalt-Catalyzed Remote Hydroboration of Enamines

  • Yuyuan Liu ,
  • Yaqin Lei ,
  • Wen Yang ,
  • Wanxiang Zhao
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  • State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082
* Corresponding authors. E-mail: ;

Received date: 2023-02-25

  Revised date: 2023-05-14

  Online published: 2023-05-15

Supported by

National Natural Science Foundation of China(22271086); National Natural Science Foundation of China(21971059)

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Abstract

A cobalt-catalyzed remote hydroboration of enamines via a sequence of chain walking and hydroboration in the presence of an earth abundant catalyst and a commercially available ligand is reported, providing a rapid access to borylamines. This protocol exhibites mild reaction conditions, broad substrate scope and good functional group compatibility. In addition, the practicability and the potential synthesis value of this reaction were demonstrated by a gram reaction and a variety of synthetic transformations of the borylamine products.

Key words： cobalt; enamines; remote hydroboration; bornic esters

Cite this article

Yuyuan Liu , Yaqin Lei , Wen Yang , Wanxiang Zhao . Cobalt-Catalyzed Remote Hydroboration of Enamines[J]. Chinese Journal of Organic Chemistry, 2023 , 43(5) : 1761 -1771 . DOI: 10.6023/cjoc202302027

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