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Chinese Journal of Organic Chemistry >

2023 , Vol. 43 >Issue 10: 3635 - 3643

DOI: https://doi.org/10.6023/cjoc202304035

Nickel-Catalyzed [4＋2] Cyclization of Benzosilacyclobutenes and Acylsilanes

  • Weilu Zhang ,
  • Shaowei Chen ,
  • Xiao Shen
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  • a Institute for Advanced Studies, Wuhan University, Wuhan 430072
    b Engineering Research Center of Organosilicon Compounds & Materials, Ministry of Education, Wuhan 430072
*E-mail:

Received date: 2023-04-28

  Revised date: 2023-06-24

  Online published: 2023-07-13

Supported by

National Key R&D Program of China(2022YFA1506100); Fundamental Research Funds for the Central Universities(2042023kf1010); Fundamental Research Funds for the Central Universities(2042023kf0202); National Natural Science Foundation of China(21901191)

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Abstract

A nickel-catalyzed [4＋2] cyclization reaction between benzosilacyclobutenes and acylsilanes for the synthesis of cyclic bissilanes is reported. The mild reaction showes good substrate scope and the products can be transformed to monoaclohols or diols via one-step down-stream transformations.

Key words： nickel catalysis; benzosilacyclobutene; acylsilane; cycloaddition; C—Si bond activation

Cite this article

Weilu Zhang , Shaowei Chen , Xiao Shen . Nickel-Catalyzed [4＋2] Cyclization of Benzosilacyclobutenes and Acylsilanes[J]. Chinese Journal of Organic Chemistry, 2023 , 43(10) : 3635 -3643 . DOI: 10.6023/cjoc202304035

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