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Chinese Journal of Organic Chemistry >

2023 , Vol. 43 >Issue 12: 4268 - 4276

DOI: https://doi.org/10.6023/cjoc202305024

ARTICLES

Organic-Dye-Catalyzed Visible-Light-Mediated Alkoxycarbon-ylation of 2-Aryl-N-acryloyl Indoles with Carbazates

  • Changyuan Du ,
  • Yucai Tang ,
  • Jinglin Duan ,
  • Biyu Yang ,
  • Yupeng He ,
  • Qian Zhou ,
  • Xuewen Liu
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  • Hunan Provincial Key Laboratory of Water Treatment Functional Materials, Hunan Province Engineering Research Center of Electroplating Wastewater Reuse Technology, College of Chemistry and Materials Engineering, Hunan University of Arts and Science, Changde, Hunan 415000
*

Received date: 2023-05-17

  Revised date: 2023-07-04

  Online published: 2023-07-27

Supported by

Hunan Provincial Natural Science Foundation of China(2020JJ5390); Hunan Provincial Natural Science Foundation of China(2022JJ30418); Key Research Project of Hunan University of Arts and Science(21ZD07); Innovation and Entrepreneurship Training Program for College Students(XDC202318)

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Abstract

A visible-light-mediated organic dye photoredox-catalyzed alkoxycarbonylation of 2-aryl-N-acryloyl indoles to give valuable indolo[2,1-a]isoquinoline derivatives has been developed. With this approach, a variety of ester-substituted indolo[2,1-a]isoquinolines are prepared in moderate to good yields. Mild reaction conditions, metal free, visible light as a traceless energy source, economical and environmentally benign Rose Bengal as the catalyst, stable and easily accessible starting materials all make this methodology more attractive.

Key words： Rose Bengal; organic dye; visible-light; 2-aryl-indoles; indolo[2,1-a]isoquinolines

Cite this article

Changyuan Du , Yucai Tang , Jinglin Duan , Biyu Yang , Yupeng He , Qian Zhou , Xuewen Liu . Organic-Dye-Catalyzed Visible-Light-Mediated Alkoxycarbon-ylation of 2-Aryl-N-acryloyl Indoles with Carbazates[J]. Chinese Journal of Organic Chemistry, 2023 , 43(12) : 4268 -4276 . DOI: 10.6023/cjoc202305024

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