Chinese Journal of Organic Chemistry >
Recent Advances in Transition Metal-Catalyzed C—Si Bond Cleavage of Silacyclobutanes
Received date: 2023-06-22
Revised date: 2023-08-25
Online published: 2023-08-30
Supported by
National Natural Science Foundation of China(22022103); National Natural Science Foundation of China(22071114)
Due to the widespread application of various organosilicon compounds in material science, electronic devices and pharmaceutical research, it is of great significance to develop green and efficient synthetic methods for diverse silicon-con- taining molecules. Silacyclobutane is an important kind of small-membered rings, which exhibits unique reactivities under transition metal catalysis to cleave the C—Si bond driven by the inherent ring strain and Lewis acidity. The resulting Si—M species can then be transformed into various organosilicon compounds. Herein, the recent advances of Pd, Rh, and Ni-catalyzed C—Si bond cleavage reactions of silacyclobutanes are summarized in detail, and the mechanism and development tendency of such reactions are briefly discussed.
Key words： transition metal catalysis; silacyclobutane; C—Si bond cleavage
Min Liu , Liping Qi , Dongbing Zhao . Recent Advances in Transition Metal-Catalyzed C—Si Bond Cleavage of Silacyclobutanes[J]. Chinese Journal of Organic Chemistry, 2023 , 43(10) : 3508 -3525 . DOI: 10.6023/cjoc202306019
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