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Chinese Journal of Organic Chemistry >

2024 , Vol. 44 >Issue 4: 1124 - 1150

DOI: https://doi.org/10.6023/cjoc202309012

REVIEWS

Recent Advances in Transition-Metal-Catalyzed C—S Bond Activation and Transformations

  • Kaijie Guo ,
  • Xinshu Fu ,
  • Jing Li ,
  • Yan Chen ,
  • Meili Hu ,
  • Xihua Du ,
  • Yuyang Xie ,
  • Yan He
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  • a School of Materials and Chemical Engineering, Xuzhou University of Technology, Xuzhou, Jiangsu 221018
    b Jiangsu Key Laboratory of New Drug Research and Clinical Pharmacy, Xuzhou Medical University, Xuzhou, Jiangsu 221004
* E-mail: ;

Received date: 2023-09-11

  Revised date: 2023-12-06

  Online published: 2023-12-18

Supported by

Scientific Research Project of Xuzhou(KC21286); Xuzhou University of Technology “Great Innovation Plan” Project in 2022(xcx2022013)

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Abstract

The activation of C—S bond plays a crucial role in the preparation of drug molecules, high-performance polymers and composite materials, as well as in biomedical, environmental protection and other fields. Transition-metal-catalyzed C—S bond activation and transformations have a wide range of application prospects. Herein, the recent advances in transition-metal-catalyzed C(sp)/C(sp2)/C(sp3)—S bond activation and transformations are summarized according to the hybridization types of carbon atoms in organosulfur compounds. Various transition metal catalysts are utilized. The substrate applicability and reaction mechanisms are emphatically discussed. Finally, the challenges and future development trends of this research field are discussed and prospected.

Key words： C—S bond activation; transition metal catalysis; organosulfur compounds

Cite this article

Kaijie Guo , Xinshu Fu , Jing Li , Yan Chen , Meili Hu , Xihua Du , Yuyang Xie , Yan He . Recent Advances in Transition-Metal-Catalyzed C—S Bond Activation and Transformations[J]. Chinese Journal of Organic Chemistry, 2024 , 44(4) : 1124 -1150 . DOI: 10.6023/cjoc202309012

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