Chinese Journal of Organic Chemistry >
Recent Advance in Electrochemical C(sp2)—H Amination of Arenes
Received date: 2023-10-31
Revised date: 2023-12-13
Online published: 2024-01-05
Supported by
National Key Research and Development Program of China(2022YFA1503200); National Natural Science Foundation of China(22371149); National Natural Science Foundation of China(22188101); Fundamental Research Funds for the Central Universities(63223015); Frontiers Science Center for New Organic Matter, Nankai University(63181206)
Aniline and its derivatives are widely used and consumed in human life and industrial production, which inspires the direct aromatic C(sp2)—N construction from the corresponding C(sp2)—H bond. In recent years, as a controllable, sustainable, ambient, and highly scalable methodology, organic electrochemistry has received greater attention and also combined aromatic C(sp2)—N amination, presenting novel reactions. In this review, the common mechanism manifolds of electrochemical aromatic C(sp2)—H amination reactions are summarized, and the reactions examples are classified according to the type of amine sources. The prospects and challenges in this field are provided.
Key words： electrochemistry; amination; arene; aniline; C—H amination
Zile Zhu , Pengfei Li , Youai Qiu . Recent Advance in Electrochemical C(sp2)—H Amination of Arenes[J]. Chinese Journal of Organic Chemistry, 2024 , 44(3) : 871 -891 . DOI: 10.6023/cjoc202310033
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