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Chinese Journal of Organic Chemistry >

2024 , Vol. 44 >Issue 7: 2063 - 2076

DOI: https://doi.org/10.6023/cjoc202403017

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Transition Metal Catalyzed Carbocycle-Selective Asymmetric Hydrogenation of Aromatic Rings

  • Qian Chen ,
  • Zhaobin Han ,
  • Kuiling Ding
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  • a School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093
    b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
    c School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240
    d Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240
* E-mail: ;

Received date: 2024-03-12

  Revised date: 2024-04-13

  Online published: 2024-04-25

Supported by

National Key R&D Program of China(2021YFA1500200); National Natural Science Foundation of China(21872167); Program of Shanghai Academic/Technology Research Leader(22XD1424800)

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Abstract

Asymmetric hydrogenation of carbon rings in (hetero)arenes is one of the most direct and efficient methods for preparing saturated and partially saturated chiral six membered carbon ring compounds. While significant challenges in terms of low reactivity and selectivity remain, some breakthroughs have been made in this field of carbocycle-selective asymmetric hydrogenation of (hetero)arenes in recent years. The research progress of transition metal catalyzed carbocycle-selective asymmetric hydrogenation of (hetero)arenes in the past few decades is summarized, and the prospects of further developments are also discussed.

Key words： transition metal; (hetero)arene; asymmetric hydrogenation; dearomatization

Cite this article

Qian Chen , Zhaobin Han , Kuiling Ding . Transition Metal Catalyzed Carbocycle-Selective Asymmetric Hydrogenation of Aromatic Rings[J]. Chinese Journal of Organic Chemistry, 2024 , 44(7) : 2063 -2076 . DOI: 10.6023/cjoc202403017

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