Chinese Journal of Organic Chemistry >
Synthesis of New Rh-Cp Complex with an Ester Group Tethered on the Cp Ring and Its Application in the Catalytic Synthesis of iso-Quinolines
Received date: 2024-02-28
Revised date: 2024-04-09
Online published: 2024-04-30
A new type of cyclopentadienyl metal rhodium catalyst was synthesized by introducing an ester functional group onto the cyclopentadienyl group. The catalyst was evaluated with C—H active [4＋2] annulation of aryl oximes and alkynes. The result demonstrated that the new catalyst was superior to conventional catalysts [Cp*RhCl2]2 in terms of reactivity and the usage of the metal acetate added.
Key words： iso-quinoline; Rh-Cp complex; [4＋2] annulation; oxime; alkyne
Huan Jin , Yanjun Zhu , Fang Li , Yunfei Luo . Synthesis of New Rh-Cp Complex with an Ester Group Tethered on the Cp Ring and Its Application in the Catalytic Synthesis of iso-Quinolines[J]. Chinese Journal of Organic Chemistry, 2024 , 44(9) : 2906 -2914 . DOI: 10.6023/cjoc202402014
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