Chinese Journal of Organic Chemistry >
Boryl Radical-Promoted Synthesis of Biaryls and Benzylcarboxylic Acids Methyl Ester via C—C Bond Formation Reactions
Received date: 2024-02-22
Revised date: 2024-03-24
Online published: 2024-05-11
Supported by
Natural Science Foundation of Gansu Province(22JR5RM203); Doctor Foundation of Longdong University(XYBYZK2221); Doctor Foundation of Longdong University(XYBYZK2224); Youth Scientific and Technical Innovation Foundation of Longdong University(XYZK2303); Innovation Fund Project of Gansu Education Department(2024A-164)
A facile route for the formation of C—C bonds with tetraarylborates as boryl radical precursors under organophotoredox conditions is developed. This strategy has been verified to be applicable not only for the preparation of symmetrical and unsymmetrical biaryls, but also for direct carboxylation of a range of free benzyl alcohols. Control experiments and mechanism studies indicated that aryl boron radical species is a reactive intermediate.
Wenduo Li , Na'na Wei , Nan Feng . Boryl Radical-Promoted Synthesis of Biaryls and Benzylcarboxylic Acids Methyl Ester via C—C Bond Formation Reactions[J]. Chinese Journal of Organic Chemistry, 2024 , 44(6) : 1853 -1861 . DOI: 10.6023/cjoc202402012
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