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Chinese Journal of Organic Chemistry >

2024 , Vol. 44 >Issue 8: 2523 - 2529

DOI: https://doi.org/10.6023/cjoc202404003

ARTICLES

Detection of Oxygen Based on Host-Guest Doped Room-Temperature Phosphorescence Material

  • Wei Zhang ,
  • Gengchen Li ,
  • Hao Su ,
  • Wenbo Dai ,
  • Peng Sun ,
  • Jianbing Shi ,
  • Bin Tong ,
  • Zhengxu Cai ,
  • Yuping Dong
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  • a Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081
    b Hefei National Laboratory, University of Science and Technology of China, Hefei 230088
    c College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035
    d Key Lab of Biohealth Materials and Chemistry of Wenzhou, Wenzhou University, Wenzhou, Zhejiang 325035
    e Advanced Research Institute of Multidisciplinary Sciences, Beijing Institute of Technology, Beijing 100081
† The authors contributed equally to this work.
*E-mail: ;
*E-mail: ;

Received date: 2024-04-01

  Revised date: 2024-05-31

  Online published: 2024-07-02

Supported by

National Natural Science Foundation of China(22222501); National Natural Science Foundation of China(22175023); Natural Science Foundation of Beijing(2232022); Natural Science Foundation of Beijing(2242060); Beijing Institute of Technology Research and Innovation Promoting Project(2023YCXZ016)

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Abstract

Quantitative oxygen detection, especially at low concentrations, holds significant importance in the realms of biology, complex environments, and chemical process engineering. Due to the high sensitivity and rapid response of the triplet excitons of phosphorescence to oxygen, pure organic room-temperature phosphorescence (RTP) materials have garnered widespread attention in recent years for oxygen detection. However, simultaneously achieving ultralong phosphorescence at room temperature and quantitative oxygen detection from pure organic host-guest doped materials poses challenges. The densely packed materials may decrease non-radiative decay to increase the phosphorescence, but are unsuitable for oxygen diffusion in oxygen detection. Herein, the oxygen sensitivity of host-guest doped RTP materials using 4-bromo-N,N-bis(4-(tert- butyl)phenyl)aniline (TPABuBr) as the host and 6-bromo-2-butyl-1H-benzo[de]isoquinoline-1,3(2H)-dione (NIBr) as the guest was developed. The doped material exhibits fluorescence-phosphorescence dual-emission behavior at room temperature. The tert-butyl groups in TPABuBr facilitate appropriate intermolecular spacing in the crystal state, enhancing oxygen permeability. Therefore, oxygen penetration can quench the phosphorescence emission. The observed linear relationship between the phosphorescence intensity of the doped material and the oxygen volume fraction conforms to the Stern-Volmer equation, suggesting its potential for quantitative analysis of oxygen concentration. The calculated limit of detection is 0.015% (φ), enabling the analysis of oxygen with a volume fraction of less than 2.5% (φ). Moreover, the doped materials demonstrate rapid response and excellent photostability, indicating their potential utility as oxygen sensors. This study elucidates the design and characteristics of NIBr/TPABuBr doped materials, highlighting their potential application in oxygen concentration detection and offering insights for the design of oxygen sensors.

Key words： organic room-temperature phosphorescence; host-guest doped strategy; oxygen sensitive materials; oxygen concentration detection

Cite this article

Wei Zhang , Gengchen Li , Hao Su , Wenbo Dai , Peng Sun , Jianbing Shi , Bin Tong , Zhengxu Cai , Yuping Dong . Detection of Oxygen Based on Host-Guest Doped Room-Temperature Phosphorescence Material[J]. Chinese Journal of Organic Chemistry, 2024 , 44(8) : 2523 -2529 . DOI: 10.6023/cjoc202404003

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