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Chinese Journal of Organic Chemistry >

2024 , Vol. 44 >Issue 12: 3747 - 3752

DOI: https://doi.org/10.6023/cjoc202405043

ARTICLE

Synthesis of Terminal Vinyl Phosphine Oxides via Desulfonative C—P Formation from Alkenyl Sulfonium Salts

  • Jiangzhen An ,
  • Qiyan Lv ,
  • Kai Sun ,
  • Xiaolan Chen ,
  • Lingbo Qu ,
  • Bing Yu
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  • a College of Chemistry, Zhengzhou University, Zhengzhou 450001
    b Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037
*Corresponding authors. E-mail:;

Received date: 2024-05-29

  Revised date: 2024-07-20

  Online published: 2024-08-19

Supported by

National Natural Science Foundation of China(22171249); National Natural Science Foundation of China(22071222)

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Abstract

Cesium carbonate was used as a base to achieve the desulfurization reaction of alkenyl sulfonium salts and phosphine oxides at room temperature, forming C(sp2)—P bonds. This method features simple operation, mild reaction conditions, and good functional group compatibility, offering a straightforward and efficient preparation route for terminal vinyl phosphine oxides.

Key words： desulfonative coupling; vinyl phosphine oxide; C—P bond; alkenyl sulfonium salt

Cite this article

Jiangzhen An , Qiyan Lv , Kai Sun , Xiaolan Chen , Lingbo Qu , Bing Yu . Synthesis of Terminal Vinyl Phosphine Oxides via Desulfonative C—P Formation from Alkenyl Sulfonium Salts[J]. Chinese Journal of Organic Chemistry, 2024 , 44(12) : 3747 -3752 . DOI: 10.6023/cjoc202405043

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