Chinese Journal of Organic Chemistry >
Recent Progress in the Construction of Silacycles by Transition- Metal-Catalyzed C—H Silylation
Received date: 2024-06-17
Revised date: 2024-07-19
Online published: 2024-08-26
Supported by
National Natural Science Foundation of China(22271260); National Natural Science Foundation of China(22301285); Key Projects of the Joint Fund for Science and Technology of Henan Province(232301420007); Natural Science Foundation of Henan Province(242300421033); Natural Science Foundation of Henan Province(242300421120); China Postdoctoral Science Foundation(2023M743166)
Silacycles are essential structural motifs in silicon-containing functional molecules, which are widely used in the fields of synthetic chemistry, pharmaceutical and material science. As such, the development of efficient synthetic methods for these structurally diverse scaffolds is of great significance. Among these, due to its high atomic economy and step economy properties, transition-metal-catalyzed direct C—H silylation provides a powerful and straightforward synthetic method to form diverse silacycles. In this review, the recent progress in the construction of silacycles by transition-metal-catalyzed C(sp2)—H and C(sp3)—H silylation reactions is summarized.
Key words： silacycles; transition-metal; C—H activation; silylation; organosilicon compounds
Zeshui Liu , Zhenzhen Guo , Junlong Niu . Recent Progress in the Construction of Silacycles by Transition- Metal-Catalyzed C—H Silylation[J]. Chinese Journal of Organic Chemistry, 2025 , 45(2) : 423 -447 . DOI: 10.6023/cjoc202406022
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