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Chinese Journal of Organic Chemistry >

2024 , Vol. 44 >Issue 10: 3178 - 3184

DOI: https://doi.org/10.6023/cjoc202405045

ARTICLES

Synthesis of CO2-Based Re-processable Slight Cross-Linked Polyurea Thermosets

  • Wenhan Huang ,
  • Shan Jiang ,
  • Hui Li ,
  • Fengyu Zhao ,
  • Haiyang Cheng
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  • a Jilin Provincial Key Laboratory of Green Chemistry and Process, State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022
    b School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026
    c School of Materials Science and Engineering, Shanghai University, Shanghai 200444
†These authors contributed equally to this work
*E-mail: ;

Received date: 2024-05-29

  Revised date: 2024-08-22

  Online published: 2024-09-10

Supported by

National Natural Science Foundation of China(22172155)

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Abstract

The use of CO2 as monomer to synthesize polymer materials is an important and potential applications topic from the viewpoint of green and sustainable chemistry. A new kind of CO2-based polyurea (PUa) was synthesized by polycondensation of CO2 with 4,7,10-trioxa-1,13-tridecanediamine and tris(2-aminoethyl)amine (TAEA). TAEA was used as cross-link reagent. The mechanical properties of PUa were significantly improved by inserted the crosslink agent of TAEA. The formed slight cross-linked PUa exhibited excellent mechanical properties with tensile strength of 26.8 MPa, elongation at break of 34% and Young’s modulus of 351 MPa. Moreover, it could be remolded for 3 times without obvious change in the mechanical properties, which are ascribed to the hydrogen bonding interaction among the main chains and the slight cross-linked structure. In addition, the synthesized CO2-based PUa is of outstanding thermal performance with an initial decomposition temperature above 300 ℃, besides it is tolerance for a variety of organic solvents.

Key words： CO2; polyurea; non-isocyanate; re-processable; thermoset; slight cross-linking

Cite this article

Wenhan Huang , Shan Jiang , Hui Li , Fengyu Zhao , Haiyang Cheng . Synthesis of CO2-Based Re-processable Slight Cross-Linked Polyurea Thermosets[J]. Chinese Journal of Organic Chemistry, 2024 , 44(10) : 3178 -3184 . DOI: 10.6023/cjoc202405045

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