Chinese Journal of Organic Chemistry >
Transition Metal-Catalyzed Asymmetric Migratory Allylic C—H Functionalization of Remote Dienes
Received date: 2024-06-29
Revised date: 2024-07-26
Online published: 2024-09-10
Supported by
National Natural Science Foundation of China(22071262); National Natural Science Foundation of China(22371292); Science and Technology Commission of Shanghai Municipality(22ZR1475200); Natural Science Foundation of Ningbo(2023J036); Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0610000)
Asymmetric allylic C—H functionalization is a valuable and challenging research area. Different from the conventional direct allylic C—H cleavage strategy, transition metal-catalyzed migratory allylic substitution of remote dienes has emerged as a new route to achieve allylic C—H functionalization enantioselectively. This review provides a detailed summary of the development and advance of this strategy, introduces the related mechanistic processes, and discusses the area based on the types of catalysts and products.
Jingming Zhang , Zhitao He . Transition Metal-Catalyzed Asymmetric Migratory Allylic C—H Functionalization of Remote Dienes[J]. Chinese Journal of Organic Chemistry, 2025 , 45(2) : 592 -601 . DOI: 10.6023/cjoc202406047
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