Chinese Journal of Organic Chemistry >
Research Progress on Carbonylation Involving Name Reactions
Received date: 2024-06-28
Revised date: 2024-09-04
Online published: 2024-09-30
Supported by
National Natural Science Foundation of China for Young Scientists(21901250)
The carbonylation of carbon monoxide (CO) or carbon dioxide (CO2) catalyzed by transition metals is one of the effective strategies to construct high-value added chemicals, such as aldehydes, esters, amides, carboxylic acids, alcohols, etc. This reaction combines C1 chemical and petrochemical industries closely with the advantages of “atomic economy” and environmental friendliness. The organic name reaction is an important tool for constructing complex organic molecules. Based on the importance of organic name reactions and the significant application of carbonylation in these reactions, the research progress in recent years through the development of new catalytic systems for carbonylation is reviewed, including Reppe reaction, carbonylation coupling reaction, Alper carbonylation reaction, Pauson-Khand reaction, Gattermann-Koch formylation reaction, Koch-Haaf carbonylation reaction, Semmelhack reaction, and Wakamatsu reaction. Finally, the development and difficulties of carbonylation in organic synthesis are discussed in order to provide reference for promoting the generation of new carbonylation processes and achieving industrial transformation.
Yaowei Wang , Peng Wang , Huibing Shi , Chengfu Zhang , Deming Zhao , Guiai Yang , Yaozong Yan , Baolin Feng . Research Progress on Carbonylation Involving Name Reactions[J]. Chinese Journal of Organic Chemistry, 2025 , 45(1) : 104 -135 . DOI: 10.6023/cjoc202406043
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