Chinese Journal of Organic Chemistry >
Recent Progress in Metal-Catalyzed Asymmetric Hydroarylation of Internal Alkenes Through C—H Cleavage
Received date: 2024-06-29
Revised date: 2024-09-09
Online published: 2024-10-11
Supported by
National Natural Science Foundation of China(22371160)
Abstract Catalytic asymmetric addition of aryl C—H bonds to alkenes is an effective method for constructing benzylic chiral centers, offering advantages such as readily available starting materials, high atom economy, and diverse product structures. The study of the addition of aryl C—H bonds to terminal alkenes began earlier and has made significant progress. In contrast, research on the asymmetric addition of aryl C—H bonds to internal alkenes has been relatively lagging behind. The recent advances in metal-catalyzed asymmetric addition of aryl C—H bonds to internal alkenes are reviewed.
Enze Lin , Bijie Li . Recent Progress in Metal-Catalyzed Asymmetric Hydroarylation of Internal Alkenes Through C—H Cleavage[J]. Chinese Journal of Organic Chemistry, 2025 , 45(2) : 546 -558 . DOI: 10.6023/cjoc202406049
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