Chinese Journal of Organic Chemistry >
Properties Research of Poly(vinyl alcohol) Phosphorescent Films Doped with 9-Fluorenyl Methoxycarbonyl-Tyrosine at Room Temperature
Received date: 2024-09-03
Revised date: 2024-10-21
Online published: 2024-11-28
Supported by
National Natural Science Foundation of China(21777113)
Room temperature phosphorescent (RTP) materials have broad application prospects in information encryption, optical sensing, biological imaging, information storage and so on. However, the realization of long-lived, high-efficiency phosphorescence in organic materials at room temperature represents a challenge, largely because the phosphorescence emission of organic molecules under ambient conditions is often hindered by intensive non-radiative transitions, inefficient intersystem crossing, and quenching of oxygen. In this study, the doped polymer matrix strategy was mainly used to achieve long-life room temperature phosphorescence emission. Two kinds of 9-fluorenyl methoxycarbonyl (Fmoc)-Tyrosine@PVA films prepared can produce phosphorescence emission with a lifetime of more than 4000 ms and blue afterglow with a long duration of 41 s after irradiation by 275 nm ultraviolet light source. Furthermore, Rhodamine B, a dye molecule, was doped in the system to adjust the color of the doped films by Förster-resonance energy transfer process.
Yulan Gao , Jiangqin Long , Qiusheng Wang . Properties Research of Poly(vinyl alcohol) Phosphorescent Films Doped with 9-Fluorenyl Methoxycarbonyl-Tyrosine at Room Temperature[J]. Chinese Journal of Organic Chemistry, 2025 , 45(4) : 1261 -1267 . DOI: 10.6023/cjoc202409005
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