氟氮共掺杂多孔碳纳米片的制备及其储钾性能研究

doi:10.6023/A22120494

化学学报 ›› 2023, Vol. 81 ›› Issue (4): 319-327.DOI: 10.6023/A22120494 上一篇下一篇

研究论文

氟氮共掺杂多孔碳纳米片的制备及其储钾性能研究

蒋江民^a^,^b, 郑欣冉^a, 孟雅婷^a, 贺文杰^d, 陈亚鑫^a, 庄全超^a, 袁加仁^c^,^*(), 鞠治成^a^,^*(), 张校刚^b^,^*()

a 中国矿业大学材料与物理学院徐州 221116
b 南京航空航天大学材料科学与技术学院南京 211106
c 南昌大学物理与材料学院南昌 330038
d 河南理工大学材料科学与工程学院焦作 454003

投稿日期:2022-12-12 发布日期:2023-03-28
基金资助:
国家自然科学基金(22209204); 国家自然科学基金(22279162); 国家自然科学基金(21975283); 江苏省自然科学基金(BK20221140); 中国博士后科学基金(2022M713364)

Research on the Preparation and Potassium Storage Performance of F, N Co-doped Porous Carbon Nanosheets

Jiangmin Jiang^a^,^b, Xinran Zheng^a, Yating Meng^a, Wenjie He^d, Yaxin Chen^a, Quanchao Zhuang^a, Jiaren Yuan^c^,^*(), Zhicheng Ju^a^,^*(), Xiaogang Zhang^b^,^*()

a School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, China
b School of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China
c School of Physics and Materials, Nanchang University, Nanchang 330038, China
d School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, China

Received:2022-12-12 Published:2023-03-28
Contact: * E-mail: jryuan@ncu.edu.cn; juzc@cumt.edu.cn; azhangxg@nuaa.edu.cn
Supported by:
National Natural Science Foundation of China(22209204); National Natural Science Foundation of China(22279162); National Natural Science Foundation of China(21975283); Natural Science Foundation of Jiangsu Province(BK20221140); China Postdoctoral Science Foundation(2022M713364)

文章分享

1. Supporting Information-A22120494.pdf(1044KB)

摘要/Abstract

钾离子电容器是一种新型的电化学储能器件, 碳基材料被认为是最有前途的储钾候选材料之一. 然而, K⁺半径较大使得迁移速率缓慢, 脱嵌过程中材料的结构易破坏, 导致性能显著下降. 因此, 开发出低成本的碳材料来适应K⁺扩散的热力学与动力学需求, 已成为当前发展的瓶颈. 煤沥青是煤焦油经蒸馏提取液体馏分后得到的残余物, 它的组成主要为稠环芳烃, 具有高的含碳量、可塑性好、资源集中、价格低廉等显著优点, 是一种优质的碳基材料前驱体. 鉴于此, 本工作采用煤沥青作为碳源、聚四氟乙烯为氟源, 氯化钠为模板剂, 通过直接高温碳化的策略制备了氟氮共掺杂的多孔碳纳米片(FNCPC). 研究表明, 纳米片层的结构设计有效缩短了离子的传输路径, F、N共掺杂拓宽了碳的层间距, 缓解了体积膨胀问题, 并且形成更多的表面缺陷, 可为K⁺的存储提供更多的反应活性位点. 此外, 电化学动力学分析和密度泛函理论(DFT)表明, FNCPC具备显著的赝电容特性和强的对K吸附能. 得益于结构和化学性质的协同优化, FNCPC负极展现出优异的储钾能力(2 A•g^-1电流密度下具有212.8 mAh•g^-1的比容量)和循环稳定性. 进一步将商业化活性炭(AC)为正极, FNCPC为负极构筑了钾离子电容器(AC//FNCPC), 该器件能实现最大的能量密度为87.5 Wh•kg^-1, 并且在循环3000次后具有86.1%的容量保持率, 展现出广阔的应用前景.

关键词: 钾离子电容器, 碳纳米片, 煤沥青, 氟氮共掺杂, 吸附能

Potassium-ion capacitor (PIC) is a new type of electrochemical energy storage device, and carbon-based materials are considered as one of the most promising candidate anode materials for K⁺ storage. However, the migration rate of K⁺ is slow and the material structure is easy to be damaged during the intercalation and de-intercalation processes because the K⁺ has a larger radius, resulting in a significant decline in performance. Therefore, the development of low-cost carbon materials to meet the thermodynamic and kinetic requirements of K⁺ diffusion has become the bottleneck of current development. In this work, the F and N co-doped porous carbon nanosheets (FNCPC) were prepared by direct high-temperature carbonization, in which the low-cost coal pitch as the carbon source, polytetrafluoroethylene as the fluorine source and sodium chloride as the template agent. The structure design of the nanosheet effectively shortens the transport path of ions, and the co-doping of F and N widens the layer spacing of carbon, alleviates the volume expansion problem, and also forms more surface defects, which provides more reactive sites for K⁺ storage. In addition, electrochemical kinetic analysis and density functional theory (DFT) show that the FNCPC has remarkable pseudocapacitance characteristics and strong K adsorption energy. Benefiting from the synergistic optimization of structure and chemical properties, the FNCPC anode exhibits excellent potassium storage capacity (a high specific capacity of 212.8 mAh•g^-1 at 2 A•g^-1) and good cyclic stability. Furthermore, the PIC (AC//FNCPC) was constructed by using commercial activated carbon (AC) as cathode electrode and FNCPC as anode electrode, which delivers a maximum energy density of 87.5 Wh•kg^-1, and has a capacity retention rate of 86.1% after 3000 cycles, showing a very broad application prospect.

Key words: potassium-ion capacitor, carbon nanosheet, coal tar pitch, fluorine nitrogen co-doping, adsorption energy

引用此文

蒋江民, 郑欣冉, 孟雅婷, 贺文杰, 陈亚鑫, 庄全超, 袁加仁, 鞠治成, 张校刚. 氟氮共掺杂多孔碳纳米片的制备及其储钾性能研究[J]. 化学学报, 2023, 81(4): 319-327.

Jiangmin Jiang, Xinran Zheng, Yating Meng, Wenjie He, Yaxin Chen, Quanchao Zhuang, Jiaren Yuan, Zhicheng Ju, Xiaogang Zhang. Research on the Preparation and Potassium Storage Performance of F, N Co-doped Porous Carbon Nanosheets[J]. Acta Chimica Sinica, 2023, 81(4): 319-327.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

图/表 5

图1. (a) CPC, (b) NCPC, (c) FCPC和(d) FNCPC的扫描电子显微镜(SEM)照片. FNCPC的(e, f) TEM照片及相对应的(g) C, (h) O, (i) N和(j) F元素的EDS能谱图

Figure 1. SEM images of (a) CPC, (b) NCPC, (c) FCPC and (d) FNCPC. (e, f) TEM images of FNCPC and the corresponding (g) C, (h) O, (i) N and (j) F elemental mapping

图2. CPC、NCPC、FCPC和FNCPC的(a) XRD和(b) Raman图谱. FNCPC的(c) C 1s, (d) N1s和(e) F 1s的分峰拟合图以及(f)氮气吸附-脱附等温曲线及其孔径分布图

Figure 2. (a) XRD patterns and (b) Raman spectra of the CPC, NCPC, FCPC and FNCPC. High-resolution XPS spectra of (c) C 1s, (d) N 1s and (e) F 1s of the FNCPC. (f) N2 adsorption-desorption isotherms and pore diameter distribution of the FNCPC

图3. CPC和FNCPC的(a, b) CV曲线, (c)奈奎斯特曲线以及(d, e)充放电曲线. 煤沥青衍生碳材料的(f)倍率性能和(g, h)循环稳定性

Figure 3. (a, b) CV curves, (c) Nyquist curves, and (d, e) charge-discharge curves of CPC and FNCPC. (f) Rate performance and (g, h) cycling stability of the coal tar pitch-derived carbon materials

图4. FNCPC在不同扫速下的(a) CV曲线, (b) b值拟合曲线, (c)多扫速下的赝电容贡献, (d) 2 mV?s-1下的赝电容贡献. DFT计算中的(e) PCs, (f) NCs, (g) FCs和(h) FNCs的模型, 及其(i~l) K原子吸附在四种模型的电荷密度差. 绿色和黄色区域表示电荷差异的增强和降低(棕色, 蓝色, 红色和紫色的球分别代表C, N, F和K原子)

Figure 4. (a) CV curves, (b) b value fitted curves, (c) pseudocapacitance contribution ratios, and (d) the pseudocapacitance contribution at 2 mV?s-1 for the FNCPC. DFT calculations with the models of (e) PCs, (f) NCs, (g) FCs and (h) FNCs, respectively. Charge density difference of a K atom adsorbed on (i) PCs, (j) NCs, (k) FCs and (l) FNCs, respectively. Green and Yellow areas represent increased and decreased charge differences (brown, blue, red and purple balls represent the C, N, F and K atoms)

图5. 钾离子电容器(AC//FNCPC)的(a)器件组装示意图, (b) CV曲线, (c)充放电曲线, (d)能量密度-功率密度曲线, (e)循环性能图

Figure 5. (a) Schematic illustration of the assembled device, (b) CV curves, (c) charge-discharge curves, (d) energy-power density curves, and (e) cycling performance of the constructed PIC (AC//FNCPC)

参考文献 61

[1]	Wang, C.; Liu, T.; Yang, X.; Ge, S.; Stanley, N. V.; Rountree, E. S.; Leng, Y.; McCarthy, B. Nature 2022, 611, 485. doi: 10.1038/s41586-022-05281-0
[2]	Yang, Z.; Zhang, J.; Kintner-Meyer, M. C. W.; Lu, X.; Choi, D.; Lemmon, J. P.; Liu, J. Chem. Rev. 2011, 111, 3577. doi: 10.1021/cr100290v
[3]	Bi, S.; Banda, H.; Chen, M.; Niu, L.; Chen, M.; Wu, T.; Wang, J.; Wang, R.; Feng, J.; Chen, T.; Dinca, M.; Kornyshev, A. A.; Feng, G. Nat. Mater. 2020, 19, 552. doi: 10.1038/s41563-019-0598-7
[4]	Chang, Z.; Qiao, Y.; Yang, H.; Deng, H.; Zhu, X.; He, P.; Zhou, H. Acta Chim. Sinica 2021, 79, 139. (in Chinese) doi: 10.6023/A20090442
	(常智, 乔羽, 杨慧军, 邓瀚, 朱星宇, 何平, 周豪慎, 化学学报, 2021, 79, 139.) doi: 10.6023/A20090442
[5]	Amatucci, G. G.; Badway, F.; Du Pasquier, A.; Zheng, T. J. Electrochem. Soc. 2001, 148, A930. doi: 10.1149/1.1383553
[6]	Ding, J.; Hu, W.; Paek, E.; Mitlin, D. Chem. Rev. 2018, 118, 6457. doi: 10.1021/acs.chemrev.8b00116 pmid: 29953230
[7]	Li, B.; Zheng, J.; Zhang, H.; Jin, L.; Yang, D.; Lv, H.; Shen, C.; Shellikeri, A.; Zheng, Y.; Gong, R.; Zheng, J. P.; Zhang, C. Adv. Mater. 2018, 30, 1705670. doi: 10.1002/adma.v30.17
[8]	Aravindan, V.; Gnanaraj, J.; Lee, Y.; Madhavi, S. Chem. Rev. 2014, 114, 11619. doi: 10.1021/cr5000915
[9]	Naoi, K.; Ishimoto, S.; Miyamoto, J.; Naoi, W. Energy Environ. Sci. 2012, 5, 9363. doi: 10.1039/c2ee21675b
[10]	Shao, M.; Li, C.; Li, T.; Zhao, H.; Yu, W.; Wang, R.; Zhang, J.; Yin, L. Adv. Funct. Mater. 2020, 30, 2006561. doi: 10.1002/adfm.v30.51
[11]	Gu, X.; Hong, Y.; Ai, G.; Wang, C.; Mao, W. Acta Chim. Sinica 2018, 76, 644. (in Chinese) doi: 10.6023/A18020081
	(顾晓瑜, 洪晔, 艾果, 王朝阳, 毛文峰, 化学学报, 2018, 76, 644.) doi: 10.6023/A18020081
[12]	Wu, L.; Gu, M.; Feng, Y.; Chen, S.; Fan, L.; Yu, X.; Guo, K.; Zhou, J.; Lu, B. Adv. Funct. Mater. 2022, 32, 2109893. doi: 10.1002/adfm.v32.8
[13]	Hu, Y.; Fan, L.; Rao, A. M.; Yu, W.; Zhuoma, C.; Feng, Y.; Qin, Z.; Zhou, J.; Lu, B. Natl. Sci. Rev. 2022, 9, nwac134. doi: 10.1093/nsr/nwac134
[14]	Fan, L.; Hu, Y.; Rao, A. M.; Zhou, J.; Hou, Z.; Wang, C.; Lu, B. Small Methods 2021, 5, 202101131.
[15]	Liu, S.; Kang, L.; Henzie, J.; Zhang, J.; Ha, J.; Amin, M. A.; Hossain, M. S. A.; Jun, S. C.; Yamauchi, Y. ACS Nano 2021, 15, 18931. doi: 10.1021/acsnano.1c08428
[16]	Dong, S.; Lv, N.; Wu, Y.; Zhu, G.; Dong, X. Adv. Funct. Mater. 2021, 31, 2100455. doi: 10.1002/adfm.v31.21
[17]	Wang, B.; Zhang, Z.; Yuan, F.; Zhang, D.; Wang, Q.; Li, W.; Li, Z.; Wu, Y. A.; Wang, W. Chem. Eng. J. 2022, 428, 131093. doi: 10.1016/j.cej.2021.131093
[18]	Zhang, D.; Li, L.; Deng, J.; Gou, Y.; Fang, J.; Cui, H.; Zhao, Y.; Shang, K. ChemSusChem 2021, 14, 1974. doi: 10.1002/cssc.v14.9
[19]	Sajjad, M.; Cheng, F.; Lu, W. RSC Adv. 2021, 11, 25450. doi: 10.1039/D1RA02445K
[20]	Liu, M.; Chang, L.; Le, Z.; Jiang, J.; Li, J.; Wang, H.; Zhao, C.; Xu, T.; Nie, P.; Wang, L. ChemSusChem 2020, 13, 5837. doi: 10.1002/cssc.v13.22
[21]	Dong, Q.; Wu, F.; Bai, Y.; Wu, C. Acta Chim. Sinica 2021, 79, 1461. (in Chinese) doi: 10.6023/A21060284
	(董瑞琪, 吴锋, 白莹, 吴川, 化学学报, 2021, 79, 1461.) doi: 10.6023/A21060284
[22]	Vaalma, C.; Buchholz, D.; Passerini, S. Curr. Opin. Electrochem. 2018, 9, 41.
[23]	Pramudita, J. C.; Sehrawat, D.; Goonetilleke, D.; Sharma, N. Adv. Energy Mater. 2017, 7, 1602911. doi: 10.1002/aenm.v7.24
[24]	Eftekhari, A.; Jian, Z.; Ji, X. ACS Appl. Mater. Interfaces 2017, 9, 4404. doi: 10.1021/acsami.6b07989
[25]	Fan, L.; Ma, R.; Zhang, Q.; Jia, X.; Lu, B. Angew. Chem., Int. Ed. 2019, 58, 10500. doi: 10.1002/anie.v58.31
[26]	Wang, J.; Wang, H.; Zang, X.; Zhai, D.; Kang, F. Batteries & Supercaps 2021, 4, 554.
[27]	Wu, X.; Chen, Y.; Xing, Z.; Lam, C. W. K.; Pang, S.; Zhang, W.; Ju, Z. Adv. Energy Mater. 2019, 9, 1900343. doi: 10.1002/aenm.v9.21
[28]	Ye, J.; Simon, P.; Zhu, Y. Natl. Sci. Rev. 2020, 7, 191. doi: 10.1093/nsr/nwz140
[29]	Kumar, R.; Sahoo, S.; Joanni, E.; Singh, R. K.; Kar, K. K. ACS Appl. Mater. Interfaces 2022, 14, 20306. doi: 10.1021/acsami.1c15934
[30]	Ding, H.; Zhou, J.; Rao, A. M.; Lu, B. Natl. Sci. Rev. 2021, 8, nwaa276. doi: 10.1093/nsr/nwaa276
[31]	Li, S.; Deng, H.; Chu, Z.; Wang, T.; Wang, L.; Zhang, Q.; Cao, J.; Cheng, Y.; Huang, Y.; Zhu, J.; Lu, B. ACS Appl. Mater. Interfaces 2021, 13, 50005. doi: 10.1021/acsami.1c15524
[32]	Sun, Y.; Wang, H.; Wei, W.; Zheng, Y.; Tao, L.; Wang, Y.; Huang, M.; Shi, J.; Shi, Z.; Mitlin, D. ACS Nano 2021, 15, 1652. doi: 10.1021/acsnano.0c09290
[33]	Deng, H.; Wang, L.; Li, S.; Zhang, M.; Wang, T.; Zhou, J.; Chen, M.; Chen, S.; Cao, J.; Zhang, Q.; Zhu, J.; Lu, B. Adv. Funct. Mater. 2021, 31, 2107246. doi: 10.1002/adfm.v31.51
[34]	Yuan, F.; Sun, H.; Zhang, D.; Li, Z.; Wang, J.; Wang, H.; Wang, Q.; Wu, Y.; Wang, B. J. Colloid Interface Sci. 2022, 611, 513. doi: 10.1016/j.jcis.2021.12.121
[35]	Li, Q.; Sun, Y.; Shi, K.; Li, J.; Jian, W.; Zhang, W.; Li, H.; Wu, M.; Dang, H.; Liu, Q. ACS Appl. Energy Mater. 2022, 5, 14401. doi: 10.1021/acsaem.2c02965
[36]	Liu, M.; Chang, L.; Wang, J.; Li, J.; Jiang, J.; Pang, G.; Wang, H.; Nie, P.; Zhao, C.; Xu, T.; Wang, L. J. Power Sources 2020, 469, 228415. doi: 10.1016/j.jpowsour.2020.228415
[37]	Li, Z.; Lin, J.; Li, B.; Yu, C.; Wang, H.; Li, Q. J. Energy Storage 2021, 44, 103437. doi: 10.1016/j.est.2021.103437
[38]	Zhang, C.; Li, Q.; Wang, T.; Miao, Y.; Qi, J.; Sui, Y.; Meng, Q.; Wei, F.; Zhu, L.; Zhang, W.; Cao, P. Nanoscale 2022, 14, 6339. doi: 10.1039/D2NR01110G
[39]	Gao, J.; Wang, G.; Wang, W.; Yu, L.; Peng, B.; El-Harairy, A.; Li, J.; Zhang, G. ACS Nano 2022, 16, 6255. doi: 10.1021/acsnano.2c00140
[40]	Ghosh, S.; Barg, S.; Jeong, S. M.; Ostrikov, K. Adv. Energy Mater. 2020, 10, 2001239. doi: 10.1002/aenm.v10.32
[41]	Huang, L.; Luo, Z.; Luo, M.; Zhang, Q.; Zhu, H.; Shi, K.; Zhu, S. J. Energy Storage 2021, 38, 102509. doi: 10.1016/j.est.2021.102509
[42]	Wang, P.; Gong, Z.; Wang, D.; Hu, R.; Ye, K.; Gao, Y.; Zhu, K.; Yan, J.; Wang, G.; Cao, D. Electrochim. Acta 2021, 389, 138799. doi: 10.1016/j.electacta.2021.138799
[43]	Zhang, T.; Mao, Z.; Shi, X.; Jin, J.; He, B.; Wang, R.; Gong, Y.; Wang, H. Energy Environ. Sci. 2022, 15, 158. doi: 10.1039/D1EE03214C
[44]	Guo, W.; Geng, C.; Sun, Z.; Jiang, J.; Ju, Z. J. Colloid Interface Sci. 2022, 623, 1075. doi: 10.1016/j.jcis.2022.05.073
[45]	Chen, Y.; Xi, B.; Huang, M.; Shi, L.; Huang, S.; Guo, N.; Li, D.; Ju, Z.; Xiong, S. Adv. Mater. 2022, 34, 2108621. doi: 10.1002/adma.v34.7
[46]	Huang, S.; Li, Z.; Wang, B.; Zhang, J.; Peng, Z.; Qi, R.; Wang, J.; Zhao, Y. Adv. Funct. Mater. 2018, 28, 1706294. doi: 10.1002/adfm.v28.10
[47]	Jiang, J.; Yuan, J; Nie, P.; Zhu, Q.; Chen, C.; He, W.; Zhang, T.; Dou, H.; Zhang, X. J. Mater. Chem. A 2020, 8, 3956. doi: 10.1039/C9TA08676E
[48]	Wei, F.; He, X.; Ma, L.; Zhang, H.; Xiao, N.; Qiu, J. Nano Micro Lett. 2020, 12, 1.
[49]	Li, S.; Liu, P.; Zheng, X.; Wu, M. Electrochim. Acta 2022, 428, 140921. doi: 10.1016/j.electacta.2022.140921
[50]	Ghosh, S.; Bhattacharjee, U.; Patchaiyappan, S.; Nanda, J.; Dudney, N. J.; Martha, S. K. Adv. Energy Mater. 2021, 11, 2100135. doi: 10.1002/aenm.v11.17
[51]	Na, W.; Jun, J.; Park, J. W.; Lee, G.; Jang, J. J. Mater. Chem. A 2017, 5, 17379. doi: 10.1039/C7TA04406B
[52]	Jiang, J.; Nie, P.; Ding, B.; Zhang, Y.; Xu, G.; Wu, L.; Dou, H.; Zhang, X. J. Mater. Chem. A 2017, 5, 23283. doi: 10.1039/C7TA05972H
[53]	Sim, Y.; Kim, S. J.; Janani, G.; Chae, Y.; Surendran, S.; Kim, H.; Yoo, S.; Seok, D. C.; Jung, Y. H.; Jeon, C.; Moon, J.; Sim, U. Appl. Surf. Sci. 2020, 507, 145157. doi: 10.1016/j.apsusc.2019.145157
[54]	Jiang, Y.; Yang, Y.; Xu, R.; Cheng, X.; Huang, H.; Shi, P.; Yao, Y.; Yang, H.; Li, D.; Zhou, X.; Chen, Q.; Feng, Y.; Rui, X.; Yu, Y. ACS Nano 2021, 15, 10217. doi: 10.1021/acsnano.1c02275
[55]	Lu, X.; Pan, X.; Fang, Z.; Zhang, D.; Xu, S.; Wang, L.; Liu, Q.; Shao, G.; Fu, D.; Teng, J.; Yang, W. ACS Appl. Mater. Interfaces 2021, 13, 41619. doi: 10.1021/acsami.1c10655
[56]	Zhuang, Q.; Yang, Z.; Zhang, L.; Cui, Y. Prog. Chem. 2020, 32, 761.
[57]	Shen, L.; Lv, H.; Chen, S.; Kopold, P.; van Aken, P. A.; Wu, X.; Maier, J.; Yu, Y. Adv. Mater. 2017, 29, 1700142. doi: 10.1002/adma.v29.27
[58]	Le, Z.; Liu, F.; Nie, P.; Li, X.; Liu, X.; Bian, Z.; Chen, G.; Wu, H. B.; Lu, Y. ACS Nano 2017, 11, 2952. doi: 10.1021/acsnano.6b08332
[59]	Valencia, F.; Romero, A. H.; Ancilotto, F.; Silvestrelli, P. L. J. Phys. Chem. B 2006, 110, 14832. doi: 10.1021/jp062126+
[60]	Jin, L.; Shen, C.; Shellikeri, A.; Wu, Q.; Zheng, J.; Andrei, P.; Zhang, J.; Zheng, J. P. Energy Environ. Sci. 2020, 13, 2341. doi: 10.1039/D0EE00807A
[61]	Li, J.; Hu, X.; Zhong, G.; Liu, Y.; Ji, Y.; Chen, J.; Wen, Z. Nano Micro Lett. 2021, 13, 1.

氟氮共掺杂多孔碳纳米片的制备及其储钾性能研究

Research on the Preparation and Potassium Storage Performance of F, N Co-doped Porous Carbon Nanosheets

RichHTML

PDF

补充材料

可视化

摘要/Abstract

引用此文

分享此文

图/表 5

参考文献 61

相关文章 7

编辑推荐

相关统计

本文评价

[1]	李燕丽, 于丹丹, 林森, 孙东飞, 雷自强. α-MnO₂纳米棒/多孔碳正极材料的制备及水系锌离子电池性能研究[J]. 化学学报, 2021, 79(2): 200-207.
[2]	赵婧, 龚俊伟, 李一举, 程魁, 叶克, 朱凯, 闫俊, 曹殿学, 王贵领. 自掺杂氮多孔交联碳纳米片在超级电容器中的应用[J]. 化学学报, 2018, 76(2): 107-112.
[3]	唐典勇, 胡建平, 吕申壮, 孙国峰, 张元勤. CO 在M₅₅ (M＝Cu, Ag, Au)团簇上吸附的密度泛函研究[J]. 化学学报, 2012, 70(08): 943-948.
[4]	赵新新, 陶向明, 宓一鸣, 吴建宝, 汪丽莉, 谭明秋. 钡原子对Ru(0001)表面氮分子吸附和解离过程的影响[J]. 化学学报, 2011, 69(19): 2201-2206.
[5]	徐信, 李志强, 张荻, 陈志新. 以苯为模块自组装合成碳纳米片[J]. 化学学报, 2010, 68(12): 1205-1209.
[6]	王三跃, 阳庆元, 仲崇立. 柔性金属-有机骨架材料中甲醇吸附和扩散的分子模拟[J]. 化学学报, 2006, 64(17): 1775-1779.
[7]	王文宁,范康年,邓景发. 分子态氧在Ag(110)面上的吸附构型、吸附态和吸附能的CM和DAM从头算研究[J]. 化学学报, 1995, 53(10): 1000-1004.