化学学报 ›› 1957, Vol. 23 ›› Issue (3): 179-187. 上一篇    下一篇

论文

汞共振辐射形成臭氧的适宜条件和量子产率

陈时伟   

  1. 兰州大学化学系
  • 投稿日期:1956-12-05 发布日期:2013-06-03

THE OPTIMUM CONDITION AND QUANTUM YIELD OF OZONE FORMATION BY MERCURY RESONANCE RADIATION

CHEN SHIH-WEI(S. W. CHEN)   

  1. Department of Chemistry, Lanchow University, Lanchow
  • Received:1956-12-05 Published:2013-06-03

(1)在一大气压下,汞共振辐射中仅1849.6Å线能直接形成臭氧,2537.5Å线则不能。(2)氧中有O4或(O2)2分子时,对光化作用形成臭氧的效果并无影响。(3)根据本实验结果,可以推知2530Å线确如Briner等所指出,不能发生光化形成臭氧作用,Wulf.Herzberg.Rollefson和Burton关于2530Å线形成臭氧的解释,也跟着失去了事实依据。在Warburg实验中可能实际起作用的为2138Å线并非2530Å线。

Under atmospheric pressure, the shorter line 1849.6Å,but not the longer line 2537.5Å,of mercury resonance radiation is responsible for ozone formation in oxygen. The presence of van der Waals molecule, O4 or (O2)2, has no influence on ozone formation.