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化学学报
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化学学报 ›› 1957, Vol. 23 ›› Issue (3): 223-229. 上一篇    下一篇

论文

醛的固体衍生物的合成Ⅱ：2-取代-1, 3-双(对-氯苄基)二氮(口五)-[1, 3]

陈茹玉1,2, 约翰·毕尔门1,2   

  1. 1. 南开大学化学系;
    2. 印第安那大学化学系
  • 投稿日期:1957-01-19 发布日期:2013-06-03

THE FORMATION OF SOLID DERIVATIVES OF ALDEHYDES：2-SUBSTITUTED-1, 3-BIS(p-CHLOROBENZYL)TETRAHYDROIMIDAZOLES

CHEN JU-YU1,2, JOHN H. BILLMAN1,2   

  1. 1. The Department of Chemistry, Nankai University;
    2. The Department of Chemistry, Indiana University
  • Received:1957-01-19 Published:2013-06-03

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1.1,2-双(对-氯苄基胺基)乙烷是鉴定醛的适宜的试剂。这二胺与一般酮不起作用。2.制备二十种新的固体1,3-双(对-氯苄基)二氮国衍生物。3.2-取代-1,3-双(对-氯苄基)二氮国可用稀盐酸分解为相应的醛和二胺的盐酸盐。此反应几为定量的。4.合成了两种新的化合物:N,N'-二乙酰-1,2-双(对-氯苄基)乙烷及N,N'-二苯甲酰-1,2-双(对-氯苄基胺基)乙烷。

(1)1,2-Bis (p-Chlorobenzylamino) ethane has been found to be a very satisfactory reagent for the identification of aldehydes. This diamine did not react with acetone or the other ketones tested. (2) Twenty new solid derivatives of 1,3-bis (p-Chlorobenzyl) tetrahydroimidazole have been prepared.