化学学报 ›› 1958, Vol. 24 ›› Issue (1): 1-12,16,17,18.    下一篇

论文

双指示电极滴定法——Ⅰ. 电流滴定曲线的理论分析

高小霞, 徐光宪   

  1. 北京大学化学系
  • 投稿日期:1957-02-27 发布日期:2013-06-03

ON THE ELECTROMETRIC TITRATIONS USING TWO IDICATOR ELECTRODES Ⅰ. A THEORETICAL INTERPRETATION OF THE “DEAD-STOP END-POINT”METHOD

KAO SHEAU-SHYA, HSU KWANG-HSIEN   

  1. Department of Chemistry, Peking University
  • Received:1957-02-27 Published:2013-06-03

(1)本文讨论只指示电极电流滴定法(永停法)的理论, 推导考虑线路电阻的且能适用於各滴定阶段的一般公式, 根据这些公式可以算出不同实验条件下的理论滴定曲线.(2)定量讨论决定终点附近电流突跃大小的各种因素, 为选择永停法的最优实验条件提供一些根据.(3)提出测定扩散电流常数的简便方法.

Theories of the "dead-stop" end-point method of titration of Foulk and Bawden have been studied recently by Delahay, Kies, Duyckaerts, Gauguin and Charlot, and Bradbury, but no conclusive remarks have been obtained by these authors as to the choice of optimum experimental conditions such as the applied voltage, the initial concentration of the solution to be titrated, the temperature, the electrode area, the stirring rate, the resistance in the circuit and the sensitivity of the galvanometer.This situation has handicapped the wide applicability of this method, although it yields accurate results and requires only inexpensive equipment.