化学学报 ›› 1958, Vol. 24 ›› Issue (3): 223-227. 上一篇    下一篇

论文

聚甲基丙烯酸甲酯混合溶剂体系Ⅰ.——在甲苯-乙醇溶液中的渗透压和粘度

钱人元1, 秦汶1, 何宝俊2, 程镕时1   

  1. 1. 中国科学院应用化学研究所;
    2. 潘阳医学院
  • 投稿日期:1957-08-26 发布日期:2013-06-03

POLYMETHYLMETHACRYLATE IN MIXED SOLVENTS Ⅰ.OSMOMETRIC AND VISCOMETRIC STUDIES IN TOLUENE-ETHANOL

CHIEN JEN-YUAN1, CHING WEN1, HO PAO-TSIN2, CHENO YUNG-SHIH1   

  1. Institute of Applied Chemistry, Academia Sinica
  • Received:1957-08-26 Published:2013-06-03

作者等使用一种全部由玻璃制成的管形渗透计,半透膜用硝化纤维素溶液涂在熔结玻璃筒的外面,经脱硝基处理后使用。玻璃筒内置溶剂,筒外置溶液。这种渗透计构造简单,操作简便,特别适合于对混合溶剂、粘度大的溶液和在几个温度下的渗透压测量。聚甲基丙烯酸甲酯一个级份(Mn=6.3×105)在甲苯-乙醇溶液里的渗透压和粘度数据(25°)指示γ=0.17(沉淀剂的体积分数)时A2和[η]都呈现最大值。各溶液的粘度都微有切变速度依赖性,与牛顿流动的偏差亦在γ=0.17附近最大。在C=1×10-3克/厘米3时的沉淀点γ=0.682

A new type all-glass osmometer of very simple construction using a sintered glass cylinder as rigid support for de-nitrated collodion membrane is described. The solvent is put inside the osmotic cell and the solution outside. Not more than 10 ml of solution is needed for a determination, while the amount of solvent used is extremely small. No special technique is required for the manipulation of the osmometer. It is especially suited for the osmometric studies with mixed solvents, for very viscous solutions and for measurements at several temperatures.