化学学报 ›› 1963, Vol. 29 ›› Issue (4): 243-248. 上一篇    下一篇

论文

氧鈾和Schiff碱的内络合物

罗勤慧   

  1. 南京大学化学系
  • 投稿日期:1962-08-18 发布日期:2013-06-03

URANYL CHELATES OF SCHIFF BASES

LO CHING-HUEI   

  1. Department of Chemistry, Nanking University
  • Received:1962-08-18 Published:2013-06-03

1.合成八种氧鈾的Schiff碱新型內絡合物,由化学分析証明皆合两分手硝酸而鈾的配位数为八.2.用热天平研究所合成的絡合物的热分解,証明硝酸分子确实位于絡合物的內界.3.测量所合成的八种絡合物的克分子电导度,証明它們与三离子盐类的电导度相近,并指出在絡合物中硝酸的氫有可能形成氫鍵.4.已测定所合成絡合物在乙醇中的溶解度.

1.Eight new chelates have been prepared from uranyl nitrate and Schiff bases, and all of them contain two molecule$ of nitric acid to satisfy coordination number of uranium which is eight in these complexes.2.Results of thermogravimetric analysis of these complexes show that the two nitric acid molecules are in the inner sphere and coordinated directly to uranium.3.Molar conductivities of the complexes in methyl alcohol and pyridine solutions have been determined and the results indicate that they resemble Ⅱ-Ⅰ type electrolytes in conductance.4.Solubilities of the complexes in ethyl alcohol at 250C have also been determined.