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化学学报
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化学学报 ›› 1965, Vol. 31 ›› Issue (2): 186-188. 上一篇    

论文

“在盐的水溶液中非电解质活度系数的研究Ⅴ.无机盐对于邻硝基苯甲酸在水中溶度的影响”一文的增订

杨旦, 黄子卿   

  1. 北京大学物理化学和胶体化学研究室
  • 投稿日期:1964-11-23 发布日期:2013-06-03

REVISION OF SOME CALCULATIONS IN “STUDIES OF ACTIVITY COEFFICIENTS OF NONELECTROLYTES IN AQUEOUS SALT SOLUTIONS. V. THE EFFECT OF SALTS ON THE SOLUBILITIES OF o-NITROBENZOIC ACID IN WATER”

YANG TAN, HUANG TZU-CHING   

  1. Research Laboratory of Physical and Colloid Chemistry, Peking University
  • Received:1964-11-23 Published:2013-06-03

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596

被引次数

1

Ⅰ.在上题的文中(以下简称文献),作者遗漏了Bates等一文,因此根据下面的假设,计算邻硝基苯甲酸(HA)在高氯酸纳水溶液中的活度系数: γHA(N2CIO4)=γ0.01HBr(NaClO4(1) γHA(NaClO4)=γ0.01HBr(NaClO4)+γNaClO4—γNaBr(2) 算出结果列于文献表2第6行(γ±即γHA(盐)的缩写),并根据这些γ±值,计算)y±,CH+,…,等值.

In the arricle of the above title [1],we missed the paper of Bates and Urmston [2] which contains the data of the activity coefficients of HCl in aqueous NaCl4 solution,γHCl[NaClO4 and calculated γ0.01HCl[NaClO4](which was taken as γHA[NaClO4],HA=o-nitro-benzoic acid) by making certain assumptions.We now take their values of γ0.01HCl[NaClO4 as γHA[NaClO4]] and recalculate the salting-out constant,k.